| Attributes | Values |
|---|
| rdf:type
| |
| Description
| - A complex trisaccharide D-GalpNAcA-(1-4)D-GlpNAc-(1-4)-D-ManpNAc (3) was prepared in a good yield (35percent) in a transglycosylation reaction catalyzed by N-acetylhexosaminidase from Talaromyces flavus using p-nitrophenyl-2-acetamido-2-deoxy D-galacto-hexodialdo-1,5-pyranoside (1) as a donor followed by the in situ oxidation of the aldehyde functionality by NaClO2. The disacharide D-GlcpNAc-(1-4)-D-ManpNAc (2) was used as galactosyl acceptor. A disaccharide D-GalpNAcA-(1-4)-D-GlcpNAc (4, 39percent) originated as a by-product in the reaction. Oligosaccharides comprising a carboxy moiety at C-6 are shown to be very efficient ligands to natural killer cell activation receptors, particularly to human receptor CD69
- A complex trisaccharide D-GalpNAcA-(1-4)D-GlpNAc-(1-4)-D-ManpNAc (3) was prepared in a good yield (35percent) in a transglycosylation reaction catalyzed by N-acetylhexosaminidase from Talaromyces flavus using p-nitrophenyl-2-acetamido-2-deoxy D-galacto-hexodialdo-1,5-pyranoside (1) as a donor followed by the in situ oxidation of the aldehyde functionality by NaClO2. The disacharide D-GlcpNAc-(1-4)-D-ManpNAc (2) was used as galactosyl acceptor. A disaccharide D-GalpNAcA-(1-4)-D-GlcpNAc (4, 39percent) originated as a by-product in the reaction. Oligosaccharides comprising a carboxy moiety at C-6 are shown to be very efficient ligands to natural killer cell activation receptors, particularly to human receptor CD69 (en)
- V dobrém výtěžku (35procent) byl připraven komplexní trisacharid D-GalpNAcA-(1-4)D-GlcpNAc-(1-4)-D-ManpNAc (3) transglykosilační reakcí katalizovanou N-acetylhexosaminidasou z Talaromyces flavus za použití p-nitrophenyl-2-acetamido-2-deoxy-D-galacto-hexodialdo-1,5-pyranosidu (1) jako donoru, následovanou in situ oxidací aldehydické funkce NaClO2. Disacharid D-GlcpNAc-(1-4)-D-ManpNAc (2) byl použit jako glykosilační akceptor. Disacharid D-GalpNAcA-(1-4)-D-GlcpNAc (4, 39 procent) vznikal jako vedlejší produkt reakce. Bylo ukázáno, že oligosacharidy obsahující karboxylovou funkční skupinu na pozici C-6 jsou dobré ligandy aktivačních receptorů NK buněk, především receptoru CD69 (cs)
|
| Title
| - N-Acetylhexosamine triad in one molecule: Chemoenzymatic introduction of 2-acetamido-2-deoxy-B-D-galactopyranosyluronic acid residue into a complex oligosacharide
- N-Acetylhexosamine triad in one molecule: Chemoenzymatic introduction of 2-acetamido-2-deoxy-B-D-galactopyranosyluronic acid residue into a complex oligosacharide (en)
- Trojice N-Acetylhexosaminů v jediné molekule: Chemoenzymatické zavádění 2-acetamido-2-deoxy-B-D-galactopyranosyluronové kyseliny do komplexního oligosacharidu (cs)
|
| skos:prefLabel
| - N-Acetylhexosamine triad in one molecule: Chemoenzymatic introduction of 2-acetamido-2-deoxy-B-D-galactopyranosyluronic acid residue into a complex oligosacharide
- N-Acetylhexosamine triad in one molecule: Chemoenzymatic introduction of 2-acetamido-2-deoxy-B-D-galactopyranosyluronic acid residue into a complex oligosacharide (en)
- Trojice N-Acetylhexosaminů v jediné molekule: Chemoenzymatické zavádění 2-acetamido-2-deoxy-B-D-galactopyranosyluronové kyseliny do komplexního oligosacharidu (cs)
|
| skos:notation
| - RIV/61388971:_____/08:00313718!RIV09-AV0-61388971
|
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(1M0505), P(GA203/05/0172), P(LC06010), P(OC 170), P(OC D25.002), Z(AV0Z50200510), Z(MSM0021620808)
|
| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
| |
| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388971:_____/08:00313718
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - talaromyces flavus; B-N-acetylhexosaminidase; galactopyranosiduronic acid (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| |
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - Journal of Molecular Catalysis B-Enzymatic
|
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Bezouška, Karel
- Bojarová, Pavla
- Elling, L.
- Křen, Vladimír
- Křenek, Karel
- Kuzma, Marek
- Petrásková, Lucie
- Namdjou, D.-J.
|
| http://linked.open...ain/vavai/riv/wos
| |
| http://linked.open...n/vavai/riv/zamer
| |
| issn
| |
| number of pages
| |
| is http://linked.open...avai/riv/vysledek
of | |
![[RDF Data]](/fct/images/sw-rdf-blue.png)
![[cxml]](/fct/images/cxml_doc.png)
![[csv]](/fct/images/csv_doc.png)
![[text]](/fct/images/ntriples_doc.png)
![[turtle]](/fct/images/n3turtle_doc.png)
![[ld+json]](/fct/images/jsonld_doc.png)
![[rdf+json]](/fct/images/json_doc.png)
![[rdf+xml]](/fct/images/xml_doc.png)
![[atom+xml]](/fct/images/atom_doc.png)
![[html]](/fct/images/html_doc.png)