About: Rhodium-catalyzed C-C Bond Cleavage Reactions

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The catalytic C-C bond activation by rhodium complexes has found a wide application in organic synthesis. The course of the reaction is usually controlled by the proper ligand environment enabling processes that are otherwise not feasible under classical conditions of organic chemistry. The C-C bond activation can be achieved by the release of ring-strain in cycloalkanes (e.g. compounds possessing three- and four-membered rings), in case of non-strained C-C bonds it could be directed by a neighboring functionality (e.g. carbonyl group), or through initial C-H activation (e.g. aldehyde decarbonylation). Many of these processes have been implemented in syntheses of various natural compounds. The use of chiral ligands has recently enabled to carry many of these reactions in an enantioselective manner. The catalytic C-C bond activation by rhodium complexes has found a wide application in organic synthesis. The course of the reaction is usually controlled by the proper ligand environment enabling processes that are otherwise not feasible under classical conditions of organic chemistry. The C-C bond activation can be achieved by the release of ring-strain in cycloalkanes (e.g. compounds possessing three- and four-membered rings), in case of non-strained C-C bonds it could be directed by a neighboring functionality (e.g. carbonyl group), or through initial C-H activation (e.g. aldehyde decarbonylation). Many of these processes have been implemented in syntheses of various natural compounds. The use of chiral ligands has recently enabled to carry many of these reactions in an enantioselective manner. (en)
Title	Rhodium-catalyzed C-C Bond Cleavage Reactions - An Update Rhodium-catalyzed C-C Bond Cleavage Reactions - An Update (en)
skos:prefLabel	Rhodium-catalyzed C-C Bond Cleavage Reactions - An Update Rhodium-catalyzed C-C Bond Cleavage Reactions - An Update (en)
skos:notation	RIV/61388963:_____/12:00378940!RIV13-AV0-61388963
http://linked.open...avai/predkladatel	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...avai/riv/aktivita	I P Z
http://linked.open...avai/riv/aktivity	I, P(LC06070), Z(AV0Z40550506), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	10
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Kotora, Martin
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	165551
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/12:00378940
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	rhodium; C-C bond cleavage; catalysis; synthesis (en)
http://linked.open.../riv/klicoveSlovo	rhodium catalysis synthesis C-C bond cleavage
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[7C66AD4BE873]
http://linked.open...i/riv/nazevZdroje	Current Organic Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	The structure and synthetic applications of transition metal complexes
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	16
http://linked.open...iv/tvurceVysledku	Kotora, Martin Nečas, D. Korotvička, A.
http://linked.open...ain/vavai/riv/wos	000304267000001
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1385-2728
number of pages	45 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Rhodium-catalyzed C-C Bond Cleavage Reactions - An Update

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