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| Description
| - The aim of the Center is to overcome a critical capacity of the participating research groups and to share experience, equipment and the methodology between them. The Center will gain new general findings concerning a structure and reactivity of newly prepared complexes and will create a base of knowledge useful for following more detailed research in this area. The aim is also to integrate students to the research work (en)
- Účelem projektu je prohloubení a zkvalitnění spolupráce mezi pracovišti zabývajícími se problematikou syntézy a charakterizace nových komplexů přechodných kovů a jejich využitím v katalýze. Pozornost je věnována především výzkumu nízkovalentních sloučenin titanu a zirkonia a jejich využití pro oligomerizaci alkenů a alkynů; využití cykloadičních a cykloisomerizačních reakcí alkynů pro syntézu biologicky aktivních a přírodních látek, syntéze nových fluorofilních ligandů a jejich katalyticky aktivních komplexů s přechodnými kovy; studiu nových karbenových a karbynových komplexů potenciálně využitelných v organické syntéze; nových katalytických systémů umožňujícím uskutečnit přechodnými kovy katalyzované reakce za velmi mírných podmínek. Rovněž budou studovány možnosti organokatalýzy katalýzy. Studentům, kteří se projektu zúčastní, se dostane komplexního vzdělání v oblasti chemie komplexů přechodných kovů a jejich praktického využití. Posílí se spolupráce mezi vysokými školami AV ČR.
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| Title
| - The structure and synthetic applications of transition metal complexes (en)
- Struktura a syntetické aplikace komplexů přechodných kovů
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| skos:notation
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| http://linked.open...avai/cep/aktivita
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| http://linked.open...kovaStatniPodpora
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| http://linked.open...ep/celkoveNaklady
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| http://linked.open...datumDodatniDoRIV
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| http://linked.open...i/cep/druhSouteze
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| http://linked.open...ep/duvernostUdaju
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| http://linked.open.../cep/fazeProjektu
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| http://linked.open...ai/cep/hlavniObor
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| http://linked.open...hodnoceniProjektu
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| http://linked.open...vai/cep/kategorie
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| http://linked.open.../cep/klicovaSlova
| - přechodné kovy, katalýza, aktivace C-C vazby, cyklotrimerizace, cyklizace, difosfinoazenové ligandy, Heckova reakce, Suzukiho reakce, supramolekulární katalýza, dimerizace terminálních alkynů, hydroaminace, titanoceny, zirkonoceny, karbenové komplexy, m (en)
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| http://linked.open...ep/partnetrHlavni
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| http://linked.open...inujicichPrijemcu
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| http://linked.open...cep/pocetPrijemcu
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| http://linked.open...ocetSpoluPrijemcu
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| http://linked.open.../pocetVysledkuRIV
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| http://linked.open...enychVysledkuVRIV
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| http://linked.open...lneniVMinulemRoce
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| http://linked.open.../prideleniPodpory
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| http://linked.open...iciPoslednihoRoku
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| http://linked.open...atUdajeProjZameru
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| http://linked.open.../vavai/cep/soutez
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| http://linked.open...usZobrazovaneFaze
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| http://linked.open...ai/cep/typPojektu
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| http://linked.open...ep/ukonceniReseni
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| http://linked.open.../cep/vedlejsiObor
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| http://linked.open...ep/zahajeniReseni
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| http://linked.open...jektu+dodavatelem
| - The Research Centre „The structure and synthetic applications of transition metal complexes“ developed new catalysts, based on transition metals, which can be used for the formation and splitting of C-C bonds, cyclization and polymerization reactions. Also new fluorophilic molecules useful for the fluorous biphasic catalysis were synthesized and new synthetic procedures for purines developed. (en)
- Centrum základního výzkumu LC06070 „Struktura a syntetické aplikace komplexů přechodných kovů“ vyvinulo nové katalyzátory na bázi přechodných kovů, které jsou využitelné pro tvorbu a štěpení C-C vazeb a pro cyklizační a polymerační reakce. Byly rovněž syntetizovány nové fluorofilní molekuly vhodné pro fluorovou bifázovou katalýzu. Nově vyvinuté postupy umožňující syntézu analogů purinových bází. (cs)
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| http://linked.open...tniCyklusProjektu
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| http://linked.open.../cep/klicoveSlovo
| - Heckova reakce
- Suzukiho reakce
- aktivace C-C vazby
- cyklizace
- cyklotrimerizace
- difosfinoazenové ligandy
- dimerizace terminálních alkynů
- hydroaminace
- karbenové komplexy
- katalýza
- supramolekulární katalýza
- titanoceny
- zirkonoceny
- přechodné kovy
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| is http://linked.open...vavai/riv/projekt
of | - Synthesis, structural characterisation and bonding in an anionic hexavanadate bearing redox-active ferrocenyl groups at the periphery
- Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes.
- Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts.
- Intramolecular alkoxide-tethered permethyltitanocene(III) complexes – synthesis and crystal structure
- Synthesis of 3-(2-Hydroxy-1-phenylethyl)- and 3-(2-Hydroxy-2-phenylethyl)adenine, DNA Adducts Derived from Styrene
- Heck Reactions of 6- and 2-Halopurines
- Copper-mediated N-arylation in the synthesis of aryladenines
- Preparation of Arylmercapturic Acids by S-Arylation of N,N?-Diacetylcystine
- Uncommon Regioselectivity in Thiacalix[4]arene Formylation
- Selective synthesis of 7-substituted purines via 7,8- dihydropurines
- Acidity of Benzoic Acids Bearing the (CO)5Cr=CN(CH3)2 Group
- Synthesis of 2-(perfluoroalkyl)ethyl potassium sulfates based on perfluorinated Grignard reagents
- New pathway to C2-symmetric atropoisomeric bipyridine N,N’-dioxides and solvent effect in enantioselective allylation of aldehydes
- The reaction of (Sp)-2-(diphenylphosphino)ferrocenecarboxylic acid with carbodiimide reagents: Characterisation of the acid anhydride and urea products
- New pyridine N-oxides as chiral organocatalysts in the asymmetric allylation of aromatic aldehydes
- Ring opening of methylenecycloalkenes via the C-C bond cleavage
- Catalytic asymmetric allylation of aliphatic aldehydes by chiral bipyridine N,N'-dioxides
- Simple and Fast Synthesis of New Axially Chiral Bipyridine N,N’-Dioxides for Highly Enantioselective Allylation of Aldehydes
- Synthesis of fluorinated brassinosteroids based on alkene cross-metathesis and preliminary biological assessment
- Cross-cyclotrimerization with two nitriles as a pathway to synthesis of unsymmetrically 3,3’-disubstituted bis(tetrahydroisoquinolines)
- Synthesis and characterisation of Dewar benze-ferrocene conjugates
- Neutral and ionic reaction mechanisms for allylation of aldehydes by bipyridine N,N’-dioxides
- Rh- and Ru-complex-catalyzed dimerization of arylethynes in aqueous environment
- Synthesis and Biochemical Characterization of a Series of 17alpha-Perfluoroalkylated Estradiols as Selective Ligands for Estrogen Receptor alpha
- HFPO Trimer-Based Alkyl Triflate, a Novel Building Block for Fluorous Chemistry. Preparation, Reactions and 19F gCOSY Analysis
- Fluorous imidazolium room-temperature ionic liquids based on HFPO trimer
- Synthesis of bis(polyfluoroalkylated)imidazolium salts as key intermediates for fluorous NHC ligands
- Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes
- The crystal structures, molecular spectra and thermal behaviour of carbamoylferrocene and ferrocenecarbonylhydrazide
- Square-planar Diphosphinoazine Rhodium(I) Amido Carbonyl Complexes with an Unsymmetrical PNP’ Pincer-type Coordination
- Palladium(II) Aryl-amido Complexes of Diphosphinoazines in Unsymmetrical PNP' Pincer-type Configuration
- Diphosphinoazine Rhodium(III) and Iridium(III) Octahedral Complexes
- Synthesis and Fluxional Behavior of New %22Haevy Fluorous%22 Cyclopentadienes.
- Structural Defects in Polyallylcarbosilane Dendrimers and Their PolyolDerivatives Characterized by NMR and MALDI-TOF Mass Spectrometry
- Synthesis of 2-Aza[6]helicene and Attempts to Synthesize 2,14-Diaza[6]helicene Utilizing MetalCatalyzed Cycloisomerization
- Phosphinoferrocenyl Carboxamides Bearing Glycine Pendant Groups : Synthesis, Palladium(II) Complexes, and Catalytic Use in Polar and Aqueous Reaction Media
- Preparation, coordination properties and catalytic use of 1'-(diphenylphosphanyl)-1-ferrocenecarboxamides bearing 2-hydroxyethyl pendant groups
- 1,2:5,6-Di-O-isopropylidene-alpha-D-3-glucofuranosyl (Rp)-2-(diphenylphosphino)ferrocene-1-carboxylate
- Synthesis of Hexahelicene and 1-Methoxyhexahelicene via Cycloisomerization of Biphenylyl-Naphthalene Derivatives
- Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium
- Preparation, coordination and catalytic use of planar-chiral monocarboxylated dppf analogues
- Synthesis, crystal structures and electrochemistry of ferrocenyl-substituted 1,3,4-oxadiazoles
- Preparation and structural characterisation of a novel ferrocene-amino acid conjugate
- Preparation of planar-chiral multidonor phosphanylferrocene carboxamides and their application as ligands for palladium-catalysed asymmetric allylic alkylation
- Synthesis and anticancer activity of chalcogenide derivatives and platinum(II) and palladium(II) complexes derived from a polar ferrocene phosphanyl-carboxamide
- Chiral Phosphanylferrocenecarboxamides with Amino Acid Pendant Groups as Ligands for Cu-Mediated Asymmetric Conjugate Additions of Diethylzinc to Chalcones - Structural Characterisation of Precursors to the Cu Catalyst
- Synthesis, structural characterisation and bonding in an anionic hexavadate bearing redox-active ferrocenyl groups at the periphery
- Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2]
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