About: Interaction of DNA with echinomycin at the mercury electrode surface as detected by impedance and chronopotentiometric measurements.     Goto   Sponge   NotDistinct   Permalink

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  • The capacitance measurements (dependence of the differential capacitance C of the electrode double layer on potential e, C-E curves, electrochemical impedance spectroscopy (EIS - frequency deoendence of the impedance Z of the electrode double layer) and constant current chronopotentiometry (depndence of dt/dE on potential E at constant current, chronopotentiometric stripping analysis - CPSA) have been used for electrochemical study of echinomycin and its interaction with single-stranded (ss) and double-stranded(ds) DNA at the hanging mercury drop electrode (HMDE). The capacitance measurement showed that echinomycin gives a pseudocapacitance redox peak strongly dependent on the a.c.voltage frequency at the potential of -0.53 V. This peak is observed with the dsDNA-echinomycin comlex as well, but not with ssDNA treated by echinomycin. Similar results were obtained using CPSA masurements. Thus capacitance measurements and CPSA can distinguish with the aid of the bis-intercalator echinomycin the ss and ds
  • The capacitance measurements (dependence of the differential capacitance C of the electrode double layer on potential e, C-E curves, electrochemical impedance spectroscopy (EIS - frequency deoendence of the impedance Z of the electrode double layer) and constant current chronopotentiometry (depndence of dt/dE on potential E at constant current, chronopotentiometric stripping analysis - CPSA) have been used for electrochemical study of echinomycin and its interaction with single-stranded (ss) and double-stranded(ds) DNA at the hanging mercury drop electrode (HMDE). The capacitance measurement showed that echinomycin gives a pseudocapacitance redox peak strongly dependent on the a.c.voltage frequency at the potential of -0.53 V. This peak is observed with the dsDNA-echinomycin comlex as well, but not with ssDNA treated by echinomycin. Similar results were obtained using CPSA masurements. Thus capacitance measurements and CPSA can distinguish with the aid of the bis-intercalator echinomycin the ss and ds (en)
  • The capacitance measurements (dependence of the differential capacitance C of the electrode double layer on potential e, C-E curves, electrochemical impedance spectroscopy (EIS - frequency deoendence of the impedance Z of the electrode double layer) and constant current chronopotentiometry (depndence of dt/dE on potential E at constant current, chronopotentiometric stripping analysis - CPSA) have been used for electrochemical study of echinomycin and its interaction with single-stranded (ss) and double-stranded(ds) DNA at the hanging mercury drop electrode (HMDE). The capacitance measurement showed that echinomycin gives a pseudocapacitance redox peak strongly dependent on the a.c.voltage frequency at the potential of -0.53 V. This peak is observed with the dsDNA-echinomycin comlex as well, but not with ssDNA treated by echinomycin. Similar results were obtained using CPSA masurements. Thus capacitance measurements and CPSA can distinguish with the aid of the bis-intercalator echinomycin the ss and ds (cs)
Title
  • Interaction of DNA with echinomycin at the mercury electrode surface as detected by impedance and chronopotentiometric measurements.
  • Interaction of DNA with echinomycin at the mercury electrode surface as detected by impedance and chronopotentiometric measurements. (en)
  • Interaction of DNA with echinomycin at the mercury electrode surface as detected by impedance and chronopotentiometric measurements. (cs)
skos:prefLabel
  • Interaction of DNA with echinomycin at the mercury electrode surface as detected by impedance and chronopotentiometric measurements.
  • Interaction of DNA with echinomycin at the mercury electrode surface as detected by impedance and chronopotentiometric measurements. (en)
  • Interaction of DNA with echinomycin at the mercury electrode surface as detected by impedance and chronopotentiometric measurements. (cs)
skos:notation
  • RIV/00216224:14310/02:00007360!RIV08-AV0-14310___
http://linked.open.../vavai/riv/strany
  • 905
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GV204/97/K084), P(IAA4004002), P(IAA4004901), P(IBS5004107), Z(AV0Z5004920)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 649392
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/02:00007360
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • electrochemical impedance spectroscopy; EIS; DNA; bis-intercalator; echinomycin (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [BB34AAFDF26D]
http://linked.open...i/riv/nazevZdroje
  • Talanta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 56
http://linked.open...iv/tvurceVysledku
  • Dvořák, Jakub
  • Hasoň, Stanislav
  • Vetterl, Vladimír
  • Jelen, František
http://linked.open...n/vavai/riv/zamer
issn
  • 0039-9140
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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