About: Synthesis of Aromatic Compounds by Catalytic C-C Bond Activation of Biphenylene or Angular [3]Phenylene

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1002/chem.201103888
Description	Substituted phenanthrenes and picenes were easily prepared by reaction of biphenylene or angular [3]phenylene with various alkynes in the presence of a catalytic amount of [IrCl(cod)]2/dppe (cod=1,5-cyclooctadiene, dppe=1,2-bis(diphenylphosphino)ethane). The reaction is based on C-C bond activation of the cyclobutane ring. The reaction tolerates the presence of bulky groups on the alkyne, such as the ferrocene moiety. In addition, a catalytic system based on [RhCl(cod)]2/dppe enabled the, hitherto unreported, reaction of biphenylene with nitriles to provide phenanthridines. Substituted phenanthrenes and picenes were easily prepared by reaction of biphenylene or angular [3]phenylene with various alkynes in the presence of a catalytic amount of [IrCl(cod)]2/dppe (cod=1,5-cyclooctadiene, dppe=1,2-bis(diphenylphosphino)ethane). The reaction is based on C-C bond activation of the cyclobutane ring. The reaction tolerates the presence of bulky groups on the alkyne, such as the ferrocene moiety. In addition, a catalytic system based on [RhCl(cod)]2/dppe enabled the, hitherto unreported, reaction of biphenylene with nitriles to provide phenanthridines. (en)
Title	Synthesis of Aromatic Compounds by Catalytic C-C Bond Activation of Biphenylene or Angular [3]Phenylene Synthesis of Aromatic Compounds by Catalytic C-C Bond Activation of Biphenylene or Angular [3]Phenylene (en)
skos:prefLabel	Synthesis of Aromatic Compounds by Catalytic C-C Bond Activation of Biphenylene or Angular [3]Phenylene Synthesis of Aromatic Compounds by Catalytic C-C Bond Activation of Biphenylene or Angular [3]Phenylene (en)
skos:notation	RIV/00216208:11310/12:10127553!RIV13-GA0-11310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	I P S Z
http://linked.open...avai/riv/aktivity	I, P(GAP207/11/0338), P(LC06070), S, Z(AV0Z40550506), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	14
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Korotvička, Aleš Kotora, Martin Císařová, Ivana Roithová, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	172952
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/12:10127553
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	rhodium; reaction mechanisms; iridium; cleavage reactions; arenes (en)
http://linked.open.../riv/klicoveSlovo	rhodium reaction mechanisms arenes cleavage reactions iridium
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[B57AB98FC0BC]
http://linked.open...i/riv/nazevZdroje	Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Reaction mechanisms in organometallic chemistry The structure and synthetic applications of transition metal complexes
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	18
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Kotora, Martin Roithová, Jana Korotvička, Aleš
http://linked.open...ain/vavai/riv/wos	000302073700011
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0947-6539
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/chem.201103888
http://localhost/t...ganizacniJednotka	11310
is http://linked.open...avai/riv/vysledek of	Synthesis of Aromatic Compounds by Catalytic C-C Bond Activation of Biphenylene or Angular [3]Phenylene

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