About: Differences in the bioaccessibility of metals/metalloids in soils from mining and smelting areas (Copperbelt, Zambia)     Goto   Sponge   NotDistinct   Permalink

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  • Differences in the total and bioaccessible concentrations of As and metals (Co, Cu, Pb, Zn) in topsoils (n = 107) from the mining and smelting areas in the Zambian Copperbelt were evaluated. The mean total concentrations of metals and As in topsoils were generally 2 to 7x higher in the smelting area, indicating significantly higher effect of smelter dust fallout on the degree of topsoil contamination. The contaminant bioaccessibility was tested by an US EPA-adopted in vitro method using a simulating gastric fluid containing a 0.4 M solution of glycine adjusted to pH 1.5 by HCl. Higher bioaccessibilities in the smelter area were observed for As and Pb, attaining 100% of the total metal/metalloid concentration. The maximum bioaccessibilities of As and Pb in the mining area were 84% and 81%, respectively. The ranges, mean and median bioaccessibilities of Co, Cu and Zn were similar for the two areas. The maximum bioaccessibilities of Co, Cu and Zn were 58-65%, 80-83% and 79-83%, respectively. The obtained data indicate that a severe health risk related to topsoil ingestion should be taken into account, especially in smelting areas.
  • Differences in the total and bioaccessible concentrations of As and metals (Co, Cu, Pb, Zn) in topsoils (n = 107) from the mining and smelting areas in the Zambian Copperbelt were evaluated. The mean total concentrations of metals and As in topsoils were generally 2 to 7x higher in the smelting area, indicating significantly higher effect of smelter dust fallout on the degree of topsoil contamination. The contaminant bioaccessibility was tested by an US EPA-adopted in vitro method using a simulating gastric fluid containing a 0.4 M solution of glycine adjusted to pH 1.5 by HCl. Higher bioaccessibilities in the smelter area were observed for As and Pb, attaining 100% of the total metal/metalloid concentration. The maximum bioaccessibilities of As and Pb in the mining area were 84% and 81%, respectively. The ranges, mean and median bioaccessibilities of Co, Cu and Zn were similar for the two areas. The maximum bioaccessibilities of Co, Cu and Zn were 58-65%, 80-83% and 79-83%, respectively. The obtained data indicate that a severe health risk related to topsoil ingestion should be taken into account, especially in smelting areas. (en)
Title
  • Differences in the bioaccessibility of metals/metalloids in soils from mining and smelting areas (Copperbelt, Zambia)
  • Differences in the bioaccessibility of metals/metalloids in soils from mining and smelting areas (Copperbelt, Zambia) (en)
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  • Differences in the bioaccessibility of metals/metalloids in soils from mining and smelting areas (Copperbelt, Zambia)
  • Differences in the bioaccessibility of metals/metalloids in soils from mining and smelting areas (Copperbelt, Zambia) (en)
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  • RIV/00216208:11310/12:10127548!RIV13-GA0-11310___
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  • I, P(GA205/08/0321), P(GAP210/12/1413), Z(MSM0021620855)
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  • FEBRUARY
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  • 131225
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  • RIV/00216208:11310/12:10127548
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  • Zambia; Copperbelt; Arsenic; metals; topsoil; Bioaccessibility (en)
http://linked.open.../riv/klicoveSlovo
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  • NL - Nizozemsko
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  • [AB1EB80C7584]
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  • Journal of Geochemical Exploration
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  • 113
http://linked.open...iv/tvurceVysledku
  • Kříbek, Bohdan
  • Majer, Vladimír
  • Mihaljevič, Martin
  • Ettler, Vojtěch
  • Knésl, Ilja
http://linked.open...ain/vavai/riv/wos
  • 000301086300008
http://linked.open...n/vavai/riv/zamer
issn
  • 0375-6742
number of pages
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  • 10.1016/j.gexplo.2011.08.001
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  • 11310
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