About: Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal     Goto   Sponge   NotDistinct   Permalink

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  • In this work, the first direct measurement of inter and intra-layer molecular self-diffusion in the smectic phases of a chiral smectogen (S)-2-methylbutyl-[4-(4%22-heptyloxyphenyl)-benzoyl-4-oxy-(S)-2-((S) -2)-benzoyl)-propionyl)]-propionate (ZLL7/*) by means of pulsed field gradient NMR is reported. Self-diffusion coefficients as low as 10 -13 m2 s-1 have been measured by combining magic echo spin decoupling with a stimulated echo sequence. The transitions among synclinic-anticlinic smectic phases are associated with a change in the self-diffusion coefficients.
  • In this work, the first direct measurement of inter and intra-layer molecular self-diffusion in the smectic phases of a chiral smectogen (S)-2-methylbutyl-[4-(4%22-heptyloxyphenyl)-benzoyl-4-oxy-(S)-2-((S) -2)-benzoyl)-propionyl)]-propionate (ZLL7/*) by means of pulsed field gradient NMR is reported. Self-diffusion coefficients as low as 10 -13 m2 s-1 have been measured by combining magic echo spin decoupling with a stimulated echo sequence. The transitions among synclinic-anticlinic smectic phases are associated with a change in the self-diffusion coefficients. (en)
Title
  • Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal
  • Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal (en)
skos:prefLabel
  • Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal
  • Translational self-diffusion in the synclinic to anticlinic phases of a ferroelectric liquid crystal (en)
skos:notation
  • RIV/68378271:_____/10:00355611!RIV11-MSM-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/09/0047), P(IAA100100911), P(OC10006), Z(AV0Z10100520)
http://linked.open...iv/cisloPeriodika
  • 23
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  • 293351
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/10:00355611
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  • chiral smectogen; echo sequences; ferroelectric liquid crystal; intra-layer; molecular self-diffusion; pulsed field gradient NMR (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [F14F6E208FB3]
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  • Soft Matter
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http://linked.open...v/svazekPeriodika
  • 6
http://linked.open...iv/tvurceVysledku
  • Glogarová, Milada
  • Domenici, V.
  • Cifelli, M.
  • Dvinskikh, S. V.
  • Veracini, A.
http://linked.open...ain/vavai/riv/wos
  • 000284313700022
http://linked.open...n/vavai/riv/zamer
issn
  • 1744-683X
number of pages
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