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  • Experimental investigation of the streaming current generated by the liquid mobile phase inside the chromatographic separation column packed with solid particles revealed that the measured streaming current changes only when the zones of analytes arew leaving the column. This characteristic can be understood from basíc electrodynamic properties of the particle-medium interface. Local double-layer compositions inside and outside the analyte zone, the corresponding electrokinetic behavior, and the dynamics of the double-layer adjustment to variations in the local composition of the flowing liquid are considered.
  • Experimental investigation of the streaming current generated by the liquid mobile phase inside the chromatographic separation column packed with solid particles revealed that the measured streaming current changes only when the zones of analytes arew leaving the column. This characteristic can be understood from basíc electrodynamic properties of the particle-medium interface. Local double-layer compositions inside and outside the analyte zone, the corresponding electrokinetic behavior, and the dynamics of the double-layer adjustment to variations in the local composition of the flowing liquid are considered. (en)
Title
  • Mechanism of streaming current generation by concentration gradients in packed-particle columns.
  • Mechanism of streaming current generation by concentration gradients in packed-particle columns. (en)
skos:prefLabel
  • Mechanism of streaming current generation by concentration gradients in packed-particle columns.
  • Mechanism of streaming current generation by concentration gradients in packed-particle columns. (en)
skos:notation
  • RIV/68081715:_____/01:25010025!RIV/2003/AV0/A25003/N
http://linked.open.../vavai/riv/strany
  • 66;73
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/99/0044), P(IAA4031703), Z(AV0Z4031919)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 686340
http://linked.open...ai/riv/idVysledku
  • RIV/68081715:_____/01:25010025
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • electrokinetics; electric double layer; electrochromatography (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [A2F1FB4050F2]
http://linked.open...i/riv/nazevZdroje
  • Journal of Colloid and Interface Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 244
http://linked.open...iv/tvurceVysledku
  • Vespalec, Radim
  • van Leeuwen, H. P.
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9797
number of pages
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