About: New aspects of buffering with multivalent weak acids in capillary zone electrophoresis: Pros and cons of the phosphate buffer.

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About: New aspects of buffering with multivalent weak acids in capillary zone electrophoresis: Pros and cons of the phosphate buffer. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	This contribution brings a theoretical study of the analytical separation performance of phosphate buffer, serving as model of buffering with multivalent weak acids. Single multivalent weak acids mimic the performance of background electrolytes with multiple co-anionic species for anionic analyses. It is shown that simple phosphate buffers may exhibit up to two regions of symmetry, of fronting as well as of tailing zones on the mobility scale inside the sample window. Moreover they may exhibit a region of enormous electromigration dispersion. This contribution brings a theoretical study of the analytical separation performance of phosphate buffer, serving as model of buffering with multivalent weak acids. Single multivalent weak acids mimic the performance of background electrolytes with multiple co-anionic species for anionic analyses. It is shown that simple phosphate buffers may exhibit up to two regions of symmetry, of fronting as well as of tailing zones on the mobility scale inside the sample window. Moreover they may exhibit a region of enormous electromigration dispersion. (en)
Title	New aspects of buffering with multivalent weak acids in capillary zone electrophoresis: Pros and cons of the phosphate buffer. New aspects of buffering with multivalent weak acids in capillary zone electrophoresis: Pros and cons of the phosphate buffer. (en)
skos:prefLabel	New aspects of buffering with multivalent weak acids in capillary zone electrophoresis: Pros and cons of the phosphate buffer. New aspects of buffering with multivalent weak acids in capillary zone electrophoresis: Pros and cons of the phosphate buffer. (en)
skos:notation	RIV/68081715:_____/00:25200033!RIV/2003/AV0/A25003/N
http://linked.open.../vavai/riv/strany	2809;2813
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/99/0044), P(IAA4031703), P(VS96021), P(VS97014), Z(AV0Z4031919)
http://linked.open...iv/cisloPeriodika	14
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Boček, Petr Gebauer, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav analytické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	719132
http://linked.open...ai/riv/idVysledku	RIV/68081715:_____/00:25200033
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	N/A (en)
http://linked.open.../riv/klicoveSlovo	N/A
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[27EAEDE5382E]
http://linked.open...i/riv/nazevZdroje	Electrophoresis
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	The use of new analytical instrumentation in research of analytical and diagnostic methods Methodology of analytical electrophoresis of samples with complex matrices Centrum for Analytical Chemistry of Molecular Structure Allelopathy of natural substances
http://linked.open...UplatneniVysledku	2000
http://linked.open...v/svazekPeriodika	21
http://linked.open...iv/tvurceVysledku	Boček, Petr Gebauer, Petr
http://linked.open...n/vavai/riv/zamer	Vyvinutí nových metod analytické chemie pro potřeby společenské praxe
issn	0173-0835
number of pages	5 (xsd:int)

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