About: Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20]

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About: Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Článek řeší problém reakce B18 skeletu s ligandy s volným elektronovým párem v oxidačním prostředí. (cs) The reaction of B10H14 with two-electron ligands L to give L2B10H12 is not mimicked by B18H22. Instead, an oxidizing agent is required to introduce a ligand onto the {B18} skeleton: thus deprotonation of syn-B18H22 in monoglyme followed by treatment with I2 and SMe2 gives [7-(SMe2)-syn-B18H20] (41%). The reaction of B10H14 with two-electron ligands L to give L2B10H12 is not mimicked by B18H22. Instead, an oxidizing agent is required to introduce a ligand onto the {B18} skeleton: thus deprotonation of syn-B18H22 in monoglyme followed by treatment with I2 and SMe2 gives [7-(SMe2)-syn-B18H20] (41%). (en)
Title	Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20] Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20] (en) Klastrová reakce obsahující makropolyhedrální borany.Reakce: syn-B18H22 s Me2S a I2 v monoglymu. Struktura: [7-(SMe2)-syn-B18H20] (cs)
skos:prefLabel	Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20] Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20] (en) Klastrová reakce obsahující makropolyhedrální borany.Reakce: syn-B18H22 s Me2S a I2 v monoglymu. Struktura: [7-(SMe2)-syn-B18H20] (cs)
skos:notation	RIV/61388980:_____/07:00080715!RIV07-GA0-61388980
http://linked.open.../vavai/riv/strany	125;128
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/05/2646), P(IAA400320601), P(LC523), Z(AV0Z40320502), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2007
http://linked.open...aciTvurceVysledku	Jelínek, Tomáš Štíbr, Bohumil Grüner, Bohumír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	431607
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/07:00080715
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	borane cluster; macropolyhedral; ligand addition (en)
http://linked.open.../riv/klicoveSlovo	ligand addition borane cluster macropolyhedral
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[237D93F17AAA]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Derivatization of ferratricarbollide Towards New p-type Semi-Conductor Dopant Materials based on New Big Boron-containing Cluster Molecules.
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	10
http://linked.open...iv/tvurceVysledku	Císařová, I. Grüner, Bohumír Jelínek, Tomáš Štíbr, Bohumil Kennedy, D. J.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1387-7003
number of pages	4 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20] Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20] Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20]

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