About: Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The reaction of ethyl cation with benzene ha's been investigated in a combined experimental and theoretical approach. Under single collision conditions, proton transfer affording protonated benzene concomitant with neutral ethene represents the major reaction channel. From pressure-dependent measurements, an absolute cross section of 7 +/- 2 angstrom(2) at hyperthermal energies (about 1.0 eV in the center of mass frame) is derived for this channel, from which a phenomenological rate constant of about 2.9 x 10(-10) cm(3) s(-1) is estimated at low energies. The energy behavior of the cross section as well as several side reactions leading to C-C coupling imply that the reaction Of C2H5+ with CA proceeds via a long-lived association product, presumably the covalently bound protonated ethylbenzene (ethylbenzenium ion). The reaction of ethyl cation with benzene ha's been investigated in a combined experimental and theoretical approach. Under single collision conditions, proton transfer affording protonated benzene concomitant with neutral ethene represents the major reaction channel. From pressure-dependent measurements, an absolute cross section of 7 +/- 2 angstrom(2) at hyperthermal energies (about 1.0 eV in the center of mass frame) is derived for this channel, from which a phenomenological rate constant of about 2.9 x 10(-10) cm(3) s(-1) is estimated at low energies. The energy behavior of the cross section as well as several side reactions leading to C-C coupling imply that the reaction Of C2H5+ with CA proceeds via a long-lived association product, presumably the covalently bound protonated ethylbenzene (ethylbenzenium ion). (en)
Title	Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry (en)
skos:prefLabel	Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry (en)
skos:notation	RIV/61388963:_____/09:00333715!RIV10-AV0-61388963
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/09/1223), P(IAA400400702), Z(AV0Z40400503), Z(AV0Z40550506), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	42
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Roithová, Jana Schröder, Detlef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	338215
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/09:00333715
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	gas phase; alkylbenzenium ions; molecule reactions (en)
http://linked.open.../riv/klicoveSlovo	gas phase alkylbenzenium ions molecule reactions
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[81D4D34B0C6F]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry A
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Investigation of ion-molecule collision processes relevant to the atmosphere of Titan Bond-forming reactions of hydrocarbon dications
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	113
http://linked.open...iv/tvurceVysledku	Schröder, Detlef Žabka, Ján Polášek, Miroslav Ascenzi, D. Roithová, Jana Tosi, P.
http://linked.open...ain/vavai/riv/wos	000270670700008
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1089-5639
number of pages	8 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 41 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software