About: Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reaction of [(eta(5)-C5Me5)TiMe3] With [(c-C5H9)(7)Si8O12(OH)] (SIPOSS) or [(c-C5H9)(7)Si7O9(OSiMe3)(OH)(2))] (DIPOSS') affords stoichiornetrically the half-sandwich titanium-disiloxy-nicthyl complexes [(eta(5)-C5Me5){(c-C5H9)(7)Si8O12O}(2) TiMe (1) and [(eta(5)-C5Me5) (c-C5H9)(7)Si7O9(OSiMe3)-O-2}TiMe] (2), respectively. Compound 2 consists orthe two stercoisonlers possessing the (eta(5)-C5Me5) ligand and OSiMe3 group in sYn- (2a) and anti-position (2b). The more abundant 2a (2a/2b approximate to 2:1) was isolated by fractional crystallization. Compounds I and 2a reacted rapidly with B(C6F5)(3) to give zwitterionic Complexes [(eta(5)-C5Me5) (c-C5H9)(7)Si8O12O}(2)Ti]((+)) (mu-Me)B(C6F5)(3)]((-)) 3 and syn-[eta(5)- C5Me5){(c-C5H9)(7)Si7O9(OSiMe3)O-2}Ti]((+))[(mu-Me)B(C6F5)(3)]((-)) (4a), respectively... Reaction of [(eta(5)-C5Me5)TiMe3] With [(c-C5H9)(7)Si8O12(OH)] (SIPOSS) or [(c-C5H9)(7)Si7O9(OSiMe3)(OH)(2))] (DIPOSS') affords stoichiornetrically the half-sandwich titanium-disiloxy-nicthyl complexes [(eta(5)-C5Me5){(c-C5H9)(7)Si8O12O}(2) TiMe (1) and [(eta(5)-C5Me5) (c-C5H9)(7)Si7O9(OSiMe3)-O-2}TiMe] (2), respectively. Compound 2 consists orthe two stercoisonlers possessing the (eta(5)-C5Me5) ligand and OSiMe3 group in sYn- (2a) and anti-position (2b). The more abundant 2a (2a/2b approximate to 2:1) was isolated by fractional crystallization. Compounds I and 2a reacted rapidly with B(C6F5)(3) to give zwitterionic Complexes [(eta(5)-C5Me5) (c-C5H9)(7)Si8O12O}(2)Ti]((+)) (mu-Me)B(C6F5)(3)]((-)) 3 and syn-[eta(5)- C5Me5){(c-C5H9)(7)Si7O9(OSiMe3)O-2}Ti]((+))[(mu-Me)B(C6F5)(3)]((-)) (4a), respectively... (en)
Title	Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane (en)
skos:prefLabel	Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane (en)
skos:notation	RIV/61388955:_____/09:00336721!RIV10-MSM-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(KAN100400701), P(LC06070), Z(AV0Z40400503), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	24
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Horáček, Michal Mach, Karel Pinkas, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	333011
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/09:00336721
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes; zwitteronic complexes (en)
http://linked.open.../riv/klicoveSlovo	Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes zwitteronic complexes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[2FADF39CB69A]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Hybride nanocomposite materials The structure and synthetic applications of transition metal complexes
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	28
http://linked.open...iv/tvurceVysledku	Mach, Karel Pinkas, Jiří Horáček, Michal Varga, V. Cisařová, I.
http://linked.open...ain/vavai/riv/wos	000272852400012
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0276-7333
number of pages	13 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane Pentamethylcyclopentadienylmethyltitanium Silsesquioxanes and Their Zwitterionic Complexes with Tris(pentafluorophenyl)borane

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