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rdf:type
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Description
| - A selected ion flow tube study has been carried out of the reactions of H3O+, NO+ and O-2(+) with 1,2-ethanediol (ethylene glycol), 1,2- and 1,3-propanediol, 1,2-, 1,3- and 1,4-butanediol, 1,5-pentanediol, 1,2-cyclopentanediol and 2-thioethanol (or 2-mercapto-ethanol, HOCH2CH2SH). The reactions of these species with H3O+ ions are assumed to proceed via exothermic proton transfer, their rate coefficients, k(c) being equal to the calculated collisional rate coefficients, k(c). On this basis, the experimental k values for most of the NO+ and O-2(+) reactions are also close to their respective k(c) values, although the k values for three of the NO+ reactions are measurably smaller than their k(c) values. In the H3O+ reactions the protonated parent ions MH+, are always minor product ions. (MH-H2O)(+), resulting from the loss of H2O from the nascent MH+ ions being the major product ions.
- A selected ion flow tube study has been carried out of the reactions of H3O+, NO+ and O-2(+) with 1,2-ethanediol (ethylene glycol), 1,2- and 1,3-propanediol, 1,2-, 1,3- and 1,4-butanediol, 1,5-pentanediol, 1,2-cyclopentanediol and 2-thioethanol (or 2-mercapto-ethanol, HOCH2CH2SH). The reactions of these species with H3O+ ions are assumed to proceed via exothermic proton transfer, their rate coefficients, k(c) being equal to the calculated collisional rate coefficients, k(c). On this basis, the experimental k values for most of the NO+ and O-2(+) reactions are also close to their respective k(c) values, although the k values for three of the NO+ reactions are measurably smaller than their k(c) values. In the H3O+ reactions the protonated parent ions MH+, are always minor product ions. (MH-H2O)(+), resulting from the loss of H2O from the nascent MH+ ions being the major product ions. (en)
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Title
| - A Selected Ion Flow Tube, SIFT, Study of the Reactions of H3O+, NO+ and O2 + Ions with a Series of Diols.
- A Selected Ion Flow Tube, SIFT, Study of the Reactions of H3O+, NO+ and O2 + Ions with a Series of Diols. (en)
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skos:prefLabel
| - A Selected Ion Flow Tube, SIFT, Study of the Reactions of H3O+, NO+ and O2 + Ions with a Series of Diols.
- A Selected Ion Flow Tube, SIFT, Study of the Reactions of H3O+, NO+ and O2 + Ions with a Series of Diols. (en)
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skos:notation
| - RIV/61388955:_____/02:54020105!RIV/2003/AV0/A54003/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/00/0632), P(GA203/02/0737), Z(AV0Z4040901)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/02:54020105
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - SIFT; - diols; - proton transfer (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - International Journal of Mass Spectrometry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Smith, D.
- Španěl, Patrik
- Wang, T.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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