About: Carotenoid response to retinal excitation and photoisomerization dynamics in xanthorhodopsin     Goto   Sponge   NotDistinct   Permalink

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  • Paper presents a comparative study of xanthorhodopsin, a proton pump with the carotenoid salinixanthin serving as an antenna, and the closely related bacteriorhodopsin. Upon excitation of retinal, xanthorhodopsin exhibits a wavy transient absorption pattern in the region between 470 and 540 nm. This signal is interpreted as due to electrochromic effect of the transient electric field of excited retinal on salinixanthin. The spectral shift decreases during the retinal dynamics through the ultrafast part of the photocycle. Differences in dynamics of bacteriorhodopsin and xanthorhodopsin are discussed.
  • Paper presents a comparative study of xanthorhodopsin, a proton pump with the carotenoid salinixanthin serving as an antenna, and the closely related bacteriorhodopsin. Upon excitation of retinal, xanthorhodopsin exhibits a wavy transient absorption pattern in the region between 470 and 540 nm. This signal is interpreted as due to electrochromic effect of the transient electric field of excited retinal on salinixanthin. The spectral shift decreases during the retinal dynamics through the ultrafast part of the photocycle. Differences in dynamics of bacteriorhodopsin and xanthorhodopsin are discussed. (en)
Title
  • Carotenoid response to retinal excitation and photoisomerization dynamics in xanthorhodopsin
  • Carotenoid response to retinal excitation and photoisomerization dynamics in xanthorhodopsin (en)
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  • Carotenoid response to retinal excitation and photoisomerization dynamics in xanthorhodopsin
  • Carotenoid response to retinal excitation and photoisomerization dynamics in xanthorhodopsin (en)
skos:notation
  • RIV/60077344:_____/11:00367254!RIV12-AV0-60077344
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  • P(GAP205/11/1164), P(ME09037), S, Z(AV0Z50510513), Z(MSM6007665808)
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  • 1-3
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  • 189195
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  • RIV/60077344:_____/11:00367254
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  • carotenoid; retinal; excited-state dynamics; xanthorhodopsin (en)
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  • NL - Nizozemsko
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  • [8F39F45F7791]
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  • Chemical Physics Letters
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  • 516
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  • Balashov, S. P.
  • Lanyi, J. K.
  • Polívka, Tomáš
  • Pullerits, T.
  • Šlouf, V.
http://linked.open...ain/vavai/riv/wos
  • 000296582400018
http://linked.open...n/vavai/riv/zamer
issn
  • 0009-2614
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.cplett.2011.09.062
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