About: An intramolecular charge transfer state of carbonyl carotenoids: implications for excited state dynamics of apo-carotenals and retinal

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About: An intramolecular charge transfer state of carbonyl carotenoids: implications for excited state dynamics of apo-carotenals and retinal Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	It is shown that the excited-state processes in retinal can be consistently explained if an ICT state is included in the relaxation scheme in polar solvents. The results show that a general relaxation scheme employed to explain excited-state dynamics of carbonyl carotenoids can be applied also to retinal. Also, the very short conjugation of retinal supports the notion of asymmetry as a key structural feature controlling the magnitude of the polarity-induced effects. It is shown that the excited-state processes in retinal can be consistently explained if an ICT state is included in the relaxation scheme in polar solvents. The results show that a general relaxation scheme employed to explain excited-state dynamics of carbonyl carotenoids can be applied also to retinal. Also, the very short conjugation of retinal supports the notion of asymmetry as a key structural feature controlling the magnitude of the polarity-induced effects. (en)
Title	An intramolecular charge transfer state of carbonyl carotenoids: implications for excited state dynamics of apo-carotenals and retinal An intramolecular charge transfer state of carbonyl carotenoids: implications for excited state dynamics of apo-carotenals and retinal (en)
skos:prefLabel	An intramolecular charge transfer state of carbonyl carotenoids: implications for excited state dynamics of apo-carotenals and retinal An intramolecular charge transfer state of carbonyl carotenoids: implications for excited state dynamics of apo-carotenals and retinal (en)
skos:notation	RIV/60077344:_____/11:00367253!RIV12-AV0-60077344
http://linked.open...avai/predkladatel	Biologické centrum AV ČR, v. v. i.
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(ME09037), Z(AV0Z50510513), Z(MSM6007665808)
http://linked.open...iv/cisloPeriodika	22
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Polívka, Tomáš
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Biologické centrum AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	185502
http://linked.open...ai/riv/idVysledku	RIV/60077344:_____/11:00367253
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	carotenoid; retinal; excited-state dynamics; charge-transfer state (en)
http://linked.open.../riv/klicoveSlovo	carotenoid charge-transfer state excited-state dynamics retinal
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[6728DAB81DA1]
http://linked.open...i/riv/nazevZdroje	Physical Chemistry Chemical Physics
http://linked.open...in/vavai/riv/obor	BO
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Excited-state processes in carbonyl-containing carotenoids and their roles in light-driven reactions in Nature
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	13
http://linked.open...iv/tvurceVysledku	Chábera, P. Frank, H. A. Kaligotla, S. Polívka, Tomáš
http://linked.open...ain/vavai/riv/wos	000290994900043
http://linked.open...n/vavai/riv/zamer	Výzkum struktury genetické informace rostlin a jejich patogenů na molekulární úrovni, indukce a analýza cílených změn genomu a plastomu a studium fotosyntetických procesů a projevů dědičnosti v interakci s prostředím a patogeny Fyzikální biologie -nové přístupy v biologickém výzkumu
issn	1463-9076
number of pages	10 (xsd:int)
http://bibframe.org/vocab/doi	10.1039/c1cp20269c
is http://linked.open...avai/riv/vysledek of	An intramolecular charge transfer state of carbonyl carotenoids: implications for excited state dynamics of apo-carotenals and retinal An intramolecular charge transfer state of carbonyl carotenoids: implications for excited state dynamics of apo-carotenals and retinal

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