About: New approaches to cluster modification in the 12-vertex metallatricarbollide series

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Otevření shluku [2-Cp-9-'BuNH-closo-2,1,7,9-FeC3B8H10] (1) (Cp = eta(5) -C5H5-), následované oxidací, generuje komplexy [2-Cp-8-'BuNH-closo-2,1,8,10-FeC3B8H10] (2), [2-Cp-4-(BuNH)-Bu-t-closo-2,1,4,12-FeC3B8H10] (3), [2-Cp-l-(BuNH)-Bu-t-closo-2,1,710-FeC3B8H10] (4), a [1-Cp-10-(BuNH)-Bu-t-closo-1,2,3,10-FeC3B7H9] (5). Jiné postupy syntézy vedly ke sloučeninám [2-Cpcloso-2,1,8,10-FeC3138H, 1] (6), [4-Cp-l-(BuNH)-Bu-t-closo-4,1,6,8,-FeC3B9H11] (7) a ke dvěma izomerním, zatím ne plně charakterizovaným sloučeninám se shlukem ve 13-vrcholu [(BuNH)-Bu-t-Cp-FeC3B9H12] (8 and 9). (c) 2005 Elsevier B.V. Všechna práva vyhrazená. (cs) Cluster opening of [2-Cp-9-'BuNH-closo-2,1,7,9-FeC3B8H10] (1) (Cp = eta(5) -C5H5-), followed by oxidation, generates complexes [2-Cp-8-'BuNH-closo-2,1,8,10-FeC3B8H10] (2), [2-Cp-4-(BuNH)-Bu-t-closo-2,1,4,12-FeC3B8H10] (3), [2-Cp-l-(BuNH)-Bu-t-closo-2,1,710-FeC3B8H10] (4), and [1-Cp-10-(BuNH)-Bu-t-closo-1,2,3,10-FeC3B7H9] (5). Another variation of the syntheses led to compounds [2-Cpcloso-2,1,8,10-FeC3138H, 1] (6), [4-Cp-l-(BuNH)-Bu-t-closo-4,1,6,8,-FeC3B9H11] (7) and to two isomeric, not yet fully characterized, 13-vertex compounds of general nido structure [(BuNH)-Bu-t-Cp-FeC3B9H12] (8 and 9). (c) 2005 Elsevier B.V. All rights reserved. Cluster opening of [2-Cp-9-'BuNH-closo-2,1,7,9-FeC3B8H10] (1) (Cp = eta(5) -C5H5-), followed by oxidation, generates complexes [2-Cp-8-'BuNH-closo-2,1,8,10-FeC3B8H10] (2), [2-Cp-4-(BuNH)-Bu-t-closo-2,1,4,12-FeC3B8H10] (3), [2-Cp-l-(BuNH)-Bu-t-closo-2,1,710-FeC3B8H10] (4), and [1-Cp-10-(BuNH)-Bu-t-closo-1,2,3,10-FeC3B7H9] (5). Another variation of the syntheses led to compounds [2-Cpcloso-2,1,8,10-FeC3138H, 1] (6), [4-Cp-l-(BuNH)-Bu-t-closo-4,1,6,8,-FeC3B9H11] (7) and to two isomeric, not yet fully characterized, 13-vertex compounds of general nido structure [(BuNH)-Bu-t-Cp-FeC3B9H12] (8 and 9). (c) 2005 Elsevier B.V. All rights reserved. (en)
Title	New approaches to cluster modification in the 12-vertex metallatricarbollide series New approaches to cluster modification in the 12-vertex metallatricarbollide series (en) Nové přístupy k modifikaci shluku ve 12-vrcholu série metallatricarbollidů (cs)
skos:prefLabel	New approaches to cluster modification in the 12-vertex metallatricarbollide series New approaches to cluster modification in the 12-vertex metallatricarbollide series (en) Nové přístupy k modifikaci shluku ve 12-vrcholu série metallatricarbollidů (cs)
skos:notation	RIV/44555601:13440/05:00004228!RIV09-MSM-13440___
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(GA203/05/2646), P(GA203/99/M037), P(LC523), S, Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	690
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Mikulášek, Libor
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Jana Evangelisty Purkyně v Ústí nad Labem / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	532644
http://linked.open...ai/riv/idVysledku	RIV/44555601:13440/05:00004228
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	boranes; carboranes; metallatricarbollides; metallatricarbaboranes (en)
http://linked.open.../riv/klicoveSlovo	boranes carboranes metallatricarbaboranes metallatricarbollides
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[0DAE2DA6D390]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Centre of molecular and crystal structures Derivatization of ferratricarbollide
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	11
http://linked.open...iv/tvurceVysledku	Mikulášek, Libor Gruner, B. Cícařová, I. Stibr, B.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	0022-328X
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	13440
is http://linked.open...avai/riv/vysledek of	New approaches to cluster modification in the 12-vertex metallatricarbollide series

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