About: Microanalysis of oligodeoxynucleotides by cathodic stripping voltammetry at amalgam-alloy surfaces in the presence of copper ions.     Goto   Sponge   NotDistinct   Permalink

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Description
  • The application of gold amalgam-alloy electrode (AuAE) for a sensitive voltammetric detection of different oligodeoxynucleotides (ODNs) containing the purine units within the ODN-chains in the presence of copper is described. The detection of ODNs is based on the following steps: (i)an acidic hydrolysis of the ODN (ahODN) samples performing the release of the purine bases from ODN-chain; (ii)an electrochemical accumulation of the complex of the purine base residues released from ODN-chain with copper ions Cu(I) (ahODN-Cu(I) complex) at the potential of reduction of copper ions Cu(II) on the amalgam-alloy electrode surfaces; (iii) finally followed the cathodic stripping of the electrochemically accumulated ahODN-Cu(I) complex from the electrode surface.
  • The application of gold amalgam-alloy electrode (AuAE) for a sensitive voltammetric detection of different oligodeoxynucleotides (ODNs) containing the purine units within the ODN-chains in the presence of copper is described. The detection of ODNs is based on the following steps: (i)an acidic hydrolysis of the ODN (ahODN) samples performing the release of the purine bases from ODN-chain; (ii)an electrochemical accumulation of the complex of the purine base residues released from ODN-chain with copper ions Cu(I) (ahODN-Cu(I) complex) at the potential of reduction of copper ions Cu(II) on the amalgam-alloy electrode surfaces; (iii) finally followed the cathodic stripping of the electrochemically accumulated ahODN-Cu(I) complex from the electrode surface. (en)
Title
  • Microanalysis of oligodeoxynucleotides by cathodic stripping voltammetry at amalgam-alloy surfaces in the presence of copper ions.
  • Microanalysis of oligodeoxynucleotides by cathodic stripping voltammetry at amalgam-alloy surfaces in the presence of copper ions. (en)
skos:prefLabel
  • Microanalysis of oligodeoxynucleotides by cathodic stripping voltammetry at amalgam-alloy surfaces in the presence of copper ions.
  • Microanalysis of oligodeoxynucleotides by cathodic stripping voltammetry at amalgam-alloy surfaces in the presence of copper ions. (en)
skos:notation
  • RIV/00216224:14310/06:00015531!RIV10-AV0-14310___
http://linked.open...avai/riv/aktivita
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  • P(IAA4004404), P(IBS5004107), P(KJB4004305), Z(AV0Z50040507)
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  • 3
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  • 485622
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  • RIV/00216224:14310/06:00015531
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  • gold amalgam-alloy electrode; platinum amalgam-alloy electrode; silver amalgam-alloy electrode; copper amalgam-alloy electrode; oligodeoxynucleotides; ODN; purine base residue-copper(I) complex; analysis of microliter volumes of ODN; ODN adsorption (en)
http://linked.open.../riv/klicoveSlovo
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  • CZ - Česká republika
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  • [471AC7DAA8CC]
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 69
http://linked.open...iv/tvurceVysledku
  • Hasoň, Stanislav
  • Vetterl, Vladimír
http://linked.open...n/vavai/riv/zamer
issn
  • 0039-9140
number of pages
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  • 14310
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