About: The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid)

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid) Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The X-ray structure determinations show that 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic) acid H4L forms both cis- and trans-O,O isomeric complexes with Co(III). Orientation of the other donor atoms indicates the formation of cis-O1,O2-trans-N1,N8-cis-O1,N4-[Co(HL)]. The kinetically preferred cis-isomer is easily formed due to the strong hydrogen bond between the neighboring phosphonic acid groups. The X-ray structure determinations show that 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic) acid H4L forms both cis- and trans-O,O isomeric complexes with Co(III). Orientation of the other donor atoms indicates the formation of cis-O1,O2-trans-N1,N8-cis-O1,N4-[Co(HL)]. The kinetically preferred cis-isomer is easily formed due to the strong hydrogen bond between the neighboring phosphonic acid groups. (en)
Title	The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid) The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid) (en)
skos:prefLabel	The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid) The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid) (en)
skos:notation	RIV/00216208:11310/01:00107042!RIV/2002/GA0/113102/N
http://linked.open.../vavai/riv/strany	324;330
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/97/0242), P(GA203/99/0067), P(GA203/99/M037), P(VS96140), Z(MSM 113100001)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2002
http://linked.open...aciTvurceVysledku	Kotek, Jan Lukeš, Ivan Císařová, Ivana Hermann, Petr Rohovec, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	675708
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/01:00107042
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	cis/trans-isomerism; cobalt(III) complexes; methylphosphonic acid (en)
http://linked.open.../riv/klicoveSlovo	methylphosphonic acid cis/trans-isomerism cobalt(III) complexes
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[6667FA13C678]
http://linked.open...i/riv/nazevZdroje	Inorganica Chimica Acta
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Detailed study of electron density and its changes in solid by X-ray diffraction Lease of crystallographic databases Centre of molecular and crystal structures Preparation and study of biologically active biopolymers and selected model-compounds
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	317
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Hermann, Petr Kotek, Jan Lukeš, Ivan Rohovec, Jan
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20113100001
issn	0020-1693
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software