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| Description
| - The project deals with the study of the preparation, chemical and physical properties, the structure, the reactivity and possible applications of organometallic C,N-chelated and Y,C,Y-bischelated (Y=N or O) complexes of both transition and main group metals and of analogous metal complexes with Y,N-ligands. Plausible use of prepared compounds in syntheses of organic and organometallic compounds (e.g. transfer of ligands and/or polar groups) and in catalysis (e.g. hydrogenation polymerization of olefins, hydroformylation) will be studied as well. (en)
- Projekt je zaměřen na komplexní studium přípravy, chemických a fyzikálních vlastností, struktury, reaktivity a potenciálních aplikací organokovových C,N-chelátových a Y,C,Y-bischelátových (Y=N nebo O) komplexů přechodných kovů a kovů hlavních skupin, a analogických chelátových komplexů kovů s ligandy typu Y,N-. Dále budou studovány možnosti využití sloučenin pro syntézu organických a organokovových sloučenin (přenos ligandů a polárních skupin) a pro katalýzu (hydrogenace, polymeraceolefinů, hydroformylace apod.).
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| Title
| - Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes (en)
- Struktura, vlastnosti a využití C,N-, a Y,C,Y-chelatovaných organokovových sloučenin a podobných komplexů kovů
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| skos:notation
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| http://linked.open...avai/cep/aktivita
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| http://linked.open...kovaStatniPodpora
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| http://linked.open...ep/celkoveNaklady
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| http://linked.open...datumDodatniDoRIV
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| http://linked.open...i/cep/druhSouteze
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| http://linked.open...ep/duvernostUdaju
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| http://linked.open.../cep/fazeProjektu
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| http://linked.open...ai/cep/hlavniObor
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| http://linked.open...hodnoceniProjektu
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| http://linked.open...vai/cep/kategorie
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| http://linked.open.../cep/klicovaSlova
| - organometallic; compounds; chelates; structure; complex; compounds; catalysis (en)
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| http://linked.open...ep/partnetrHlavni
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| http://linked.open...inujicichPrijemcu
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| http://linked.open...cep/pocetPrijemcu
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| http://linked.open...ocetSpoluPrijemcu
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| http://linked.open.../pocetVysledkuRIV
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| http://linked.open...enychVysledkuVRIV
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| http://linked.open...lneniVMinulemRoce
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| http://linked.open.../prideleniPodpory
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| http://linked.open...iciPoslednihoRoku
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| http://linked.open...atUdajeProjZameru
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| http://linked.open.../vavai/cep/soutez
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| http://linked.open...usZobrazovaneFaze
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| http://linked.open...ai/cep/typPojektu
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| http://linked.open...ep/ukonceniReseni
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| http://linked.open...ep/zahajeniReseni
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| http://linked.open...jektu+dodavatelem
| - A great number of complexes of numerous metals with a broad series of chelating ligands were synthesized and thoroughly characterized including x-ray diffraction, electrochemistry, and catalysis, with participation of students. The application of results in various fields is envisioned. The number of articles (14 published + 2 submitted) is extraordinary even on an international scale. (en)
- Byl syntetizován a zevrubně charakterizován, včetně rentgenové difrakce, elektrochemie a katalýzy, velký počet komplexů kovů se širokou škálou chelatujících ligandů, práce se účastnili také studenti. Výsledky mohou být prakticky uplatněny v různých oblastech. Počet článků (14 publikovaných + 2 zaslané) je mimořádný i v mezinárodním srovnání. (cs)
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| http://linked.open...tniCyklusProjektu
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| http://linked.open.../cep/klicoveSlovo
| - chelates
- complex
- compounds
- structure
- organometallic
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| is http://linked.open...vavai/riv/projekt
of | - Synthesis of organophosphorus compounds containing different Y,C,Y-chelating ligands. Crystal structure of P-N intramolecularly coordinated diselenoxophosphorane
- NCO - Chelated Organoantimony(III) and Organobismuth(III) Chlorides: Syntheses and Structure
- [{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure,
- Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand
- Quest for triorganotin(IV) compounds containing three C,N- and N,C,N-chelating ligands
- Intramolecularly Coordinated [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+): A Strong sigma Donor for Pt(II).
- Palladium(II) complexes of Y,C,Y-chelated phosphines: synthesis, structure, and catalytic activity in Suzuki-Miyaura reaction.
- OCO and NCO chelated derivatives of heavier group 15 elements. Study on possibility of cyclization reaction via intramolecular ether bond cleavage.
- Borane complex of amino-functionalized phosphine
- Chromiumpentacarbonyl-Coordinated Organotin(II) Cation.
- S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study
- Synthesis, structural characterization and electrochemistry of C,N-chelated organotin(IV) dicarboxylates with ferrocenyl substituents
- Phosphinimine complex of organotin(IV) compounds stabilized by O,C,O - chelating ligand
- Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling?
- Stabilization of an Intramolecularly Coordinated Stannylidenium Cation
- Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds
- Synthesis and Cytostatic activity of Pt(II) complexes of intramolecularly coordinated phosphine and stibine ligands
- O, N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl] phenolate as ligand
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| is http://linked.open...vavai/cep/projekt
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