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rdf:type
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Description
| - Oxidation of an intramolecularly coordinated phosphine ligand {2,6-((BuOCH2)-Bu-t)(2)C6H3}PPh2 (1) by Me3SiN3 provided novel silyl-phosphinimine {2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NSiMe3 (2), that can be easily hydrolysed to give stable phosphiniminium azide [{2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NH2](+) N-3(-) (3). Compound 3 was used for the synthesis of novel intramolecularly coordinated phosphinimine compound (LPh2P)-Ph-1=NH, that can be trapped by triorganotin(IV) compounds R3SnCl (R = Me, Cy) as organotin(IV)-phosphinimine complexes [{2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NH]SnR3Cl (R = Me(4), Cy(5)). Compounds 2-5 were characterized by means of elemental analyses, H-1, C-13, P-31, Sn-119 NMR spectroscopy, and compounds 3 and 4 by single crystal X-ray diffraction analysis.
- Oxidation of an intramolecularly coordinated phosphine ligand {2,6-((BuOCH2)-Bu-t)(2)C6H3}PPh2 (1) by Me3SiN3 provided novel silyl-phosphinimine {2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NSiMe3 (2), that can be easily hydrolysed to give stable phosphiniminium azide [{2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NH2](+) N-3(-) (3). Compound 3 was used for the synthesis of novel intramolecularly coordinated phosphinimine compound (LPh2P)-Ph-1=NH, that can be trapped by triorganotin(IV) compounds R3SnCl (R = Me, Cy) as organotin(IV)-phosphinimine complexes [{2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NH]SnR3Cl (R = Me(4), Cy(5)). Compounds 2-5 were characterized by means of elemental analyses, H-1, C-13, P-31, Sn-119 NMR spectroscopy, and compounds 3 and 4 by single crystal X-ray diffraction analysis. (en)
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Title
| - Phosphinimine complex of organotin(IV) compounds stabilized by O,C,O - chelating ligand
- Phosphinimine complex of organotin(IV) compounds stabilized by O,C,O - chelating ligand (en)
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skos:prefLabel
| - Phosphinimine complex of organotin(IV) compounds stabilized by O,C,O - chelating ligand
- Phosphinimine complex of organotin(IV) compounds stabilized by O,C,O - chelating ligand (en)
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skos:notation
| - RIV/00216275:25310/12:39894723!RIV13-GA0-25310___
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http://linked.open...avai/predkladatel
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/12:39894723
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - ligand; chelating; O,C,O; stabilized; compounds; organotinIV; complex; Phosphinimine (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Dostál, Libor
- Jambor, Roman
- Růžička, Aleš
- Řezníček, Tomáš
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.jorganchem.2012.08.003
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
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