About: Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The C,N-chelated tri and diorganotin(IV) chlorides react with both protic mineral acids and carboxylic acids. The nitrogen atom of the L-CN ligand (where L-CN is 2-(dimethylaminomethyl)phenyl) is thus quarternized e protonated and new Sn-X bond (X = Cl, Br, I or the remainder of the starting acid used) is simultaneously formed. The set of zwitterionic tri and diorganostannates containing protonated 2-(dimethylaminomethyl) phenyl-moiety was prepared and structurally characterized by multinuclear NMR spectroscopy and XRD techniques. In all these cases, the intramolecular N-H center dot center dot center dot X bond is present in the molecule. Despite the central tin atom remains five-coordinated (except for the [(HLH)-H-CN](+)[(n-Bu)(2)SnCl(NO3)(2)](-)) and reveals a distorted trigonal bipyramidal geometry, the Sn-119 NMR chemical shift values of these zwitterionic stannates are somewhat shifted to the higher field than corresponding starting C, N-chelated tri and diorganotin(IV) halides. The C,N-chelated tri and diorganotin(IV) chlorides react with both protic mineral acids and carboxylic acids. The nitrogen atom of the L-CN ligand (where L-CN is 2-(dimethylaminomethyl)phenyl) is thus quarternized e protonated and new Sn-X bond (X = Cl, Br, I or the remainder of the starting acid used) is simultaneously formed. The set of zwitterionic tri and diorganostannates containing protonated 2-(dimethylaminomethyl) phenyl-moiety was prepared and structurally characterized by multinuclear NMR spectroscopy and XRD techniques. In all these cases, the intramolecular N-H center dot center dot center dot X bond is present in the molecule. Despite the central tin atom remains five-coordinated (except for the [(HLH)-H-CN](+)[(n-Bu)(2)SnCl(NO3)(2)](-)) and reveals a distorted trigonal bipyramidal geometry, the Sn-119 NMR chemical shift values of these zwitterionic stannates are somewhat shifted to the higher field than corresponding starting C, N-chelated tri and diorganotin(IV) halides. (en)
Title	Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand (en)
skos:prefLabel	Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand (en)
skos:notation	RIV/00216275:25310/10:39882161!RIV11-GA0-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GAP207/10/0215), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	23
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Černošková, Eva Švec, Petr Růžička, Aleš Padělková, Zdeňka Holeček, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	293569
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/10:39882161
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	NMR spectroscopy; Crystal structure; C,N-Ligand; Zwitterion; Stannates; Organotin(IV) compounds (en)
http://linked.open.../riv/klicoveSlovo	NMR spectroscopy Crystal structure C Organotin(IV) compounds N-Ligand Stannates Zwitterion
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[1E4FC995C524]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	695
http://linked.open...iv/tvurceVysledku	Padělková, Zdeňka Růžička, Aleš Černošková, Eva Švec, Petr Holeček, Jaroslav
http://linked.open...ain/vavai/riv/wos	000282270800001
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0022-328X
number of pages	11 (xsd:int)
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand Tri- and Diorgano Stannanes Containing 2-(N,N-dimethylaminomethyl)phenyl Ligand

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software