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  • Electronic structure calculations combining the local-density approximation with an exact diagonalization of the Anderson impurity model show an intermediate 5f5-5f6-valence ground state and delocalization of the 5f5 multiplet of the Pu atom 5f shell in PuCoIn5, PuCoGa5, and δ-Pu. The 5f local magnetic moment is compensated by a moment formed in the surrounding cloud of conduction electrons. For PuCoGa5 and δ-Pu the compensation is complete, and the Anderson impurity ground state is a singlet. For PuCoIn5 the compensation is partial, and the Pu ground state is magnetic. We suggest that the unconventional d-wave superconductivity is likely mediated by the 5f-state antiferromagnetic fluctuations in PuCoIn5 and by valence fluctuations in PuCoGa5.
  • Electronic structure calculations combining the local-density approximation with an exact diagonalization of the Anderson impurity model show an intermediate 5f5-5f6-valence ground state and delocalization of the 5f5 multiplet of the Pu atom 5f shell in PuCoIn5, PuCoGa5, and δ-Pu. The 5f local magnetic moment is compensated by a moment formed in the surrounding cloud of conduction electrons. For PuCoGa5 and δ-Pu the compensation is complete, and the Anderson impurity ground state is a singlet. For PuCoIn5 the compensation is partial, and the Pu ground state is magnetic. We suggest that the unconventional d-wave superconductivity is likely mediated by the 5f-state antiferromagnetic fluctuations in PuCoIn5 and by valence fluctuations in PuCoGa5. (en)
Title
  • Unified character of correlation effects in unconventional Pu-based superconductors and δ-Pu
  • Unified character of correlation effects in unconventional Pu-based superconductors and δ-Pu (en)
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  • Unified character of correlation effects in unconventional Pu-based superconductors and δ-Pu
  • Unified character of correlation effects in unconventional Pu-based superconductors and δ-Pu (en)
skos:notation
  • RIV/68378271:_____/13:00397088!RIV14-GA0-68378271
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  • I, P(GAP204/10/0330), P(IAA100100912)
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  • 112599
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  • RIV/68378271:_____/13:00397088
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  • superconductivity; magnetism; plutonium (en)
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  • US - Spojené státy americké
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  • [D70D804310EA]
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  • Physical Review. B
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  • 87
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  • Kolorenč, Jindřich
  • Oppeneer, P. M.
  • Shick, Alexander
  • Caciuffo, R.
  • Lichtenstein, A. I.
  • Rusz, Ján
  • Katsnelson, M. I.
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  • 000313423900002
issn
  • 1098-0121
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  • 10.1103/PhysRevB.87.020505
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