About: Intramolecularly Coordinated [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+): A Strong sigma Donor for Pt(II).     Goto   Sponge   NotDistinct   Permalink

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Description
  • The synthesis of the unprecedented complex [Pt(LSn)(mý2-pyt)2Cl] (L=2,6-(Me2NCH2)2C6H3?), in which a Sn?N-coordinated stannylidenium (LSnII)+ fragment donates to a [Pt(pyt)2Cl]? anion, is reported. The natural-bond-orbital analysis revealed that the lone electron pair of the stannylidenium (LSnII)+ fragment is shared by tin and platinum atoms and the charge of the Sn atom is +1.709.
  • The synthesis of the unprecedented complex [Pt(LSn)(mý2-pyt)2Cl] (L=2,6-(Me2NCH2)2C6H3?), in which a Sn?N-coordinated stannylidenium (LSnII)+ fragment donates to a [Pt(pyt)2Cl]? anion, is reported. The natural-bond-orbital analysis revealed that the lone electron pair of the stannylidenium (LSnII)+ fragment is shared by tin and platinum atoms and the charge of the Sn atom is +1.709. (en)
Title
  • Intramolecularly Coordinated [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+): A Strong sigma Donor for Pt(II).
  • Intramolecularly Coordinated [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+): A Strong sigma Donor for Pt(II). (en)
skos:prefLabel
  • Intramolecularly Coordinated [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+): A Strong sigma Donor for Pt(II).
  • Intramolecularly Coordinated [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+): A Strong sigma Donor for Pt(II). (en)
skos:notation
  • RIV/00216275:25310/11:39891966!RIV12-GA0-25310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP207/10/0215), S, Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 27
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 205563
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/11:39891966
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • X-ray difraction; platinum; organotin(II) (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [3208410C35CA]
http://linked.open...i/riv/nazevZdroje
  • Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor
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http://linked.open...v/svazekPeriodika
  • 17
http://linked.open...iv/tvurceVysledku
  • Dostál, Libor
  • Jambor, Roman
  • Růžička, Aleš
  • Herres-Pawlis, Sonja
  • Martincová, Jana
http://linked.open...ain/vavai/riv/wos
  • 000292211300007
http://linked.open...n/vavai/riv/zamer
issn
  • 0947-6539
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/chem.201100417
http://localhost/t...ganizacniJednotka
  • 25310
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