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rdf:type
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Description
| - Reactions of double tucked-in permethyltitanocene [Ti{eta3:eta4-C5Me3(CH2)2}(eta5-C5Me5)] (1) with t-butanol or propargyl alcohol in toluene proceeded sluggishly even with excess of the alcohol and at elevated temperature. The alcoholysis of 1 with t-butanol afforded [Ti(eta5-C5Me5)(Ot-Bu)3] (3) as the major product and Ti(OtBu)4 as the minor one. The other product of the alcoholysis was pentamethylcyclopentadiene. The only isolated crystalline product was the very minor hydrolytic byproduct [{TiIII(eta5-C5Me5)2}(mu-O){TiIV(Ot-Bu)3}] (2). The alcoholysis of 1 containing traces of LiI with HOCH2C=CH, containing apparently more water than t-BuOH, gave an inseparable mixture of oily products from which several crystals of an unintended hydrolytic byproduct [{Ti(eta5-C5Me5)(OCH2C=CH)(mu-O)}3LiI] (4) were isolated. X-ray crystal structures of 2 and 4 were determined.
- Reactions of double tucked-in permethyltitanocene [Ti{eta3:eta4-C5Me3(CH2)2}(eta5-C5Me5)] (1) with t-butanol or propargyl alcohol in toluene proceeded sluggishly even with excess of the alcohol and at elevated temperature. The alcoholysis of 1 with t-butanol afforded [Ti(eta5-C5Me5)(Ot-Bu)3] (3) as the major product and Ti(OtBu)4 as the minor one. The other product of the alcoholysis was pentamethylcyclopentadiene. The only isolated crystalline product was the very minor hydrolytic byproduct [{TiIII(eta5-C5Me5)2}(mu-O){TiIV(Ot-Bu)3}] (2). The alcoholysis of 1 containing traces of LiI with HOCH2C=CH, containing apparently more water than t-BuOH, gave an inseparable mixture of oily products from which several crystals of an unintended hydrolytic byproduct [{Ti(eta5-C5Me5)(OCH2C=CH)(mu-O)}3LiI] (4) were isolated. X-ray crystal structures of 2 and 4 were determined. (en)
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Title
| - Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts.
- Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts. (en)
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skos:prefLabel
| - Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts.
- Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts. (en)
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skos:notation
| - RIV/62243136:_____/08:#0000055!RIV11-MPO-62243136
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(FT-TA3/078), P(LC06070), V, Z(AV0Z40400503), Z(MSM0021620857)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/62243136:_____/08:#0000055
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - titanium, double tucked-in titanocene, alcoholysis, crystal structures (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Collection of Czechoslovak Chemical Communications
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Císařová, I.
- Mach, Karel
- Štěpnička, P.
- Gyepes, R.
- Horáček, M.
- Varga, Vojtěch
- Pinkas, J.
- Kubišta, J.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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is http://linked.open...avai/riv/vysledek
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