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Description
| - The reaction of ethyl cation with benzene ha's been investigated in a combined experimental and theoretical approach. Under single collision conditions, proton transfer affording protonated benzene concomitant with neutral ethene represents the major reaction channel. From pressure-dependent measurements, an absolute cross section of 7 +/- 2 angstrom(2) at hyperthermal energies (about 1.0 eV in the center of mass frame) is derived for this channel, from which a phenomenological rate constant of about 2.9 x 10(-10) cm(3) s(-1) is estimated at low energies. The energy behavior of the cross section as well as several side reactions leading to C-C coupling imply that the reaction Of C2H5+ with CA proceeds via a long-lived association product, presumably the covalently bound protonated ethylbenzene (ethylbenzenium ion).
- The reaction of ethyl cation with benzene ha's been investigated in a combined experimental and theoretical approach. Under single collision conditions, proton transfer affording protonated benzene concomitant with neutral ethene represents the major reaction channel. From pressure-dependent measurements, an absolute cross section of 7 +/- 2 angstrom(2) at hyperthermal energies (about 1.0 eV in the center of mass frame) is derived for this channel, from which a phenomenological rate constant of about 2.9 x 10(-10) cm(3) s(-1) is estimated at low energies. The energy behavior of the cross section as well as several side reactions leading to C-C coupling imply that the reaction Of C2H5+ with CA proceeds via a long-lived association product, presumably the covalently bound protonated ethylbenzene (ethylbenzenium ion). (en)
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Title
| - Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry
- Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry (en)
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skos:prefLabel
| - Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry
- Reactivity of C2H5+ with Benzene: Formation of Ethylbenzenium Ions and Implications for Titan's Ionospheric Chemistry (en)
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skos:notation
| - RIV/61388963:_____/09:00333715!RIV10-AV0-61388963
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/09/1223), P(IAA400400702), Z(AV0Z40400503), Z(AV0Z40550506), Z(MSM0021620857)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388963:_____/09:00333715
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - gas phase; alkylbenzenium ions; molecule reactions (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Physical Chemistry A
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Schröder, Detlef
- Žabka, Ján
- Polášek, Miroslav
- Ascenzi, D.
- Roithová, Jana
- Tosi, P.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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is http://linked.open...avai/riv/vysledek
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