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  • Decomposition of acetylene / Co(CO)(3)(NO)mixtures induced by excimer ArF laser pulses is an efficient technique for preparation of amorphous cobalt nanoparticles encapsulated in carbon. Vacuum heating up to 900 degrees C leads to crystallization the metal core. The cobalt core crystallizes in a face-centered cubic (beta) form as revealed by X-ray and electron diffraction techniques and carbon affords graphite outer part. Properties of the Co(core) - carbon(shell)nanocomposites were examined by spectroscopy and microscopy techniques. Magnetization studies revealed paramagnetic behavior of the as-prepared amorphous deposit and superparamagnetic behavior of the annealed samples.
  • Decomposition of acetylene / Co(CO)(3)(NO)mixtures induced by excimer ArF laser pulses is an efficient technique for preparation of amorphous cobalt nanoparticles encapsulated in carbon. Vacuum heating up to 900 degrees C leads to crystallization the metal core. The cobalt core crystallizes in a face-centered cubic (beta) form as revealed by X-ray and electron diffraction techniques and carbon affords graphite outer part. Properties of the Co(core) - carbon(shell)nanocomposites were examined by spectroscopy and microscopy techniques. Magnetization studies revealed paramagnetic behavior of the as-prepared amorphous deposit and superparamagnetic behavior of the annealed samples. (en)
Title
  • Excimer Laser-Induced CVD of Carbon Encapsulated Cobalt Nanoparticles
  • Excimer Laser-Induced CVD of Carbon Encapsulated Cobalt Nanoparticles (en)
skos:prefLabel
  • Excimer Laser-Induced CVD of Carbon Encapsulated Cobalt Nanoparticles
  • Excimer Laser-Induced CVD of Carbon Encapsulated Cobalt Nanoparticles (en)
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  • RIV/68378271:_____/11:00398915!RIV14-AV0-68378271
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  • Z(AV0Z10100521), Z(AV0Z4032918), Z(AV0Z4072921)
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  • 198609
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  • RIV/68378271:_____/11:00398915
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  • amorphous cobalt nanoparticles; carbon encapsulation; magnetic properties (en)
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  • [FC580CE00585]
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  • Brno
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  • Slezská Ostrava
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  • Sborník příspěvků, pp. 126-141
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  • Dřínek, Vladislav
  • Fajgar, Radek
  • Kupčík, Jaroslav
  • Šubrt, Jan
  • Maryško, Miroslav
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  • 000306686700037
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  • TANGER
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  • 978-80-87294-27-7
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