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  • This contribution brings a theoretical study of the analytical separation performance of phosphate buffer, serving as model of buffering with multivalent weak acids. Single multivalent weak acids mimic the performance of background electrolytes with multiple co-anionic species for anionic analyses. It is shown that simple phosphate buffers may exhibit up to two regions of symmetry, of fronting as well as of tailing zones on the mobility scale inside the sample window. Moreover they may exhibit a region of enormous electromigration dispersion.
  • This contribution brings a theoretical study of the analytical separation performance of phosphate buffer, serving as model of buffering with multivalent weak acids. Single multivalent weak acids mimic the performance of background electrolytes with multiple co-anionic species for anionic analyses. It is shown that simple phosphate buffers may exhibit up to two regions of symmetry, of fronting as well as of tailing zones on the mobility scale inside the sample window. Moreover they may exhibit a region of enormous electromigration dispersion. (en)
Title
  • Sample induced phenomena in CZE.
  • Sample induced phenomena in CZE. (en)
skos:prefLabel
  • Sample induced phenomena in CZE.
  • Sample induced phenomena in CZE. (en)
skos:notation
  • RIV/68081715:_____/99:25200001!RIV/2003/AV0/A25003/N
http://linked.open.../vavai/riv/strany
  • 43;44
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z4031919)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 753294
http://linked.open...ai/riv/idVysledku
  • RIV/68081715:_____/99:25200001
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • system zones%capillary zone electrophoresis%system peaks (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [E5729DBC652D]
http://linked.open...v/mistoKonaniAkce
  • Palm Springs [US]
http://linked.open...i/riv/mistoVydani
  • Palm Springs
http://linked.open...i/riv/nazevZdroje
  • HPCE'99. 12th International Symposium on High Performance Capillary Electrophoresis & Related Microscale Techniques.
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Boček, Petr
  • Gebauer, Petr
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Neuveden
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