About: Investigation of in situ trapping of selenium and arsenic hydrides within a tungsten tube atomiser.     Goto   Sponge   NotDistinct   Permalink

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  • The capability of in situ trapping of selenium and arsenic hydrides within a bare and modified (Pd, Pt, Ir and Re) tungsten tube atomiser (WETA) was investigated by electrothermal atomic absorption spectrometry and by a radiotracer technique using Se-75 radionuclide. Low efficiency of trapping (below 5%) was found within the bare tungsten tube. On the other hand, modification with 100 mug of Pt, Ir and Re, respectively, enhanced significantly the efficiency of trapping. Platinum-treated tubes were very efficient at collecting hydrides in the low temperature range of 100-200 degreesC, reaching efficiency close to 100%. Iridium- and rhenium-treated tubes were capable of trapping hydrides in the high temperature range of 700-900 degreesC, approaching an overall efficiency of 10%. Palladium modifier caused fatal deterioration of the tungsten tube. Low- and high-temperature mechanisms of trapping on the inner tube surface were seen, which were probably related to the low temperature dissociative chemisorpt
  • The capability of in situ trapping of selenium and arsenic hydrides within a bare and modified (Pd, Pt, Ir and Re) tungsten tube atomiser (WETA) was investigated by electrothermal atomic absorption spectrometry and by a radiotracer technique using Se-75 radionuclide. Low efficiency of trapping (below 5%) was found within the bare tungsten tube. On the other hand, modification with 100 mug of Pt, Ir and Re, respectively, enhanced significantly the efficiency of trapping. Platinum-treated tubes were very efficient at collecting hydrides in the low temperature range of 100-200 degreesC, reaching efficiency close to 100%. Iridium- and rhenium-treated tubes were capable of trapping hydrides in the high temperature range of 700-900 degreesC, approaching an overall efficiency of 10%. Palladium modifier caused fatal deterioration of the tungsten tube. Low- and high-temperature mechanisms of trapping on the inner tube surface were seen, which were probably related to the low temperature dissociative chemisorpt (en)
Title
  • Investigation of in situ trapping of selenium and arsenic hydrides within a tungsten tube atomiser.
  • Investigation of in situ trapping of selenium and arsenic hydrides within a tungsten tube atomiser. (en)
skos:prefLabel
  • Investigation of in situ trapping of selenium and arsenic hydrides within a tungsten tube atomiser.
  • Investigation of in situ trapping of selenium and arsenic hydrides within a tungsten tube atomiser. (en)
skos:notation
  • RIV/68081715:_____/01:25010014!RIV/2003/AV0/A25003/N
http://linked.open.../vavai/riv/strany
  • 831;837
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/98/0754), Z(AV0Z4031919)
http://linked.open...iv/cisloPeriodika
  • 8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 683472
http://linked.open...ai/riv/idVysledku
  • RIV/68081715:_____/01:25010014
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • graphite furnace; absorption spectrometry; atomization (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [89CF506D9F70]
http://linked.open...i/riv/nazevZdroje
  • Journal of Analytical Atomic Spectrometry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 16
http://linked.open...iv/tvurceVysledku
  • Marek, Petr
  • Dočekal, Bohumil
http://linked.open...n/vavai/riv/zamer
issn
  • 0267-9477
number of pages
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