About: Transient Detection in Infrared Multiphoton Decomposition of (Chloromethyl)silane and 1,3-Disilacyclobutane: Evidence for Cleavage of SiCH4 Intermediates.

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About: Transient Detection in Infrared Multiphoton Decomposition of (Chloromethyl)silane and 1,3-Disilacyclobutane: Evidence for Cleavage of SiCH4 Intermediates. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The transients produced in the infrared multiphoton decomposition (IRMPD) of (chloromethyl)silane HClSi:, H2Si: and H2C: and of 1,3-disilacyclobutane H2Si: and H2C: have been identified by laser-induced fluorescence (LIF). The nascent HClSi: and H2Si: populations are generated with a high degree of excitation and the species produced from (chloromethyl)silane possess more rotational and vibrational energy than those produced from 1,3-disilacyclobutane. The obtained quenching rate and radiative lifetime for HClSi: are (4.6 0.3) 10-10?cm3 per molecule?s-1 and 369 10?ns, respectively. The formation of H2Si: and H2C: in IRMPD of both (chloromethyl)silane and 1,3-disilacyclobutane adds to previous knowledge on decomposition of (chloromethyl)silane and 1,3-disilacyclobutane and suggests that these transients are produced from the same SiCH4 (H3Si(H)C: and (CH3)HSi:) intermediates. The transients produced in the infrared multiphoton decomposition (IRMPD) of (chloromethyl)silane HClSi:, H2Si: and H2C: and of 1,3-disilacyclobutane H2Si: and H2C: have been identified by laser-induced fluorescence (LIF). The nascent HClSi: and H2Si: populations are generated with a high degree of excitation and the species produced from (chloromethyl)silane possess more rotational and vibrational energy than those produced from 1,3-disilacyclobutane. The obtained quenching rate and radiative lifetime for HClSi: are (4.6 0.3) 10-10?cm3 per molecule?s-1 and 369 10?ns, respectively. The formation of H2Si: and H2C: in IRMPD of both (chloromethyl)silane and 1,3-disilacyclobutane adds to previous knowledge on decomposition of (chloromethyl)silane and 1,3-disilacyclobutane and suggests that these transients are produced from the same SiCH4 (H3Si(H)C: and (CH3)HSi:) intermediates. (en)
Title	Transient Detection in Infrared Multiphoton Decomposition of (Chloromethyl)silane and 1,3-Disilacyclobutane: Evidence for Cleavage of SiCH4 Intermediates. Transient Detection in Infrared Multiphoton Decomposition of (Chloromethyl)silane and 1,3-Disilacyclobutane: Evidence for Cleavage of SiCH4 Intermediates. (en)
skos:prefLabel	Transient Detection in Infrared Multiphoton Decomposition of (Chloromethyl)silane and 1,3-Disilacyclobutane: Evidence for Cleavage of SiCH4 Intermediates. Transient Detection in Infrared Multiphoton Decomposition of (Chloromethyl)silane and 1,3-Disilacyclobutane: Evidence for Cleavage of SiCH4 Intermediates. (en)
skos:notation	RIV/67985858:_____/02:27020228!RIV/2003/AV0/A27003/N
http://linked.open.../vavai/riv/strany	17;24
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC 523.60), Z(AV0Z4072921)
http://linked.open...iv/cisloPeriodika	1-3
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Pola, Josef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	667270
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/02:27020228
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	infrared multiphoton dissociation; laser-induced fluorescence; decomposition mechanisms (en)
http://linked.open.../riv/klicoveSlovo	laser-induced fluorescence decomposition mechanisms infrared multiphoton dissociation
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[19A5ED6C1403]
http://linked.open...i/riv/nazevZdroje	Journal of Photochemistry and Photobiology, A
http://linked.open...in/vavai/riv/obor	CH
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20523.60
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	152
http://linked.open...iv/tvurceVysledku	Pola, Josef Diaz, L. Santos, M.
http://linked.open...n/vavai/riv/zamer	Theoretical fundamentals of chemical processes: equilibrium and dynamic behavior of multiphase reacting systems
issn	1010-6030
number of pages	8 (xsd:int)

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