About: Partial Molar Liquidus Temperatures of Multivalent Elements in Multicomponent Borosilicate Glass.

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About: Partial Molar Liquidus Temperatures of Multivalent Elements in Multicomponent Borosilicate Glass. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The oxidation-reduction equilibrium of Fe in a multicomponent borosilicate glass containing several multivalent elements (Fe, Ni, Cr, Mn) and precipitating spinel was measured over a range of imposed oxygen partial pressures ( ) [10-14 Pa to 105 Pa] and temperatures (T) [850 C to 1300 C] with Mössbauer spectroscopy and wet colorimetry. These data were combined with oxidation-reduction equilibria for Fe, Ni, Cr, and Mn in a borosilicate frit of a similar composition found in the literature to estimate concentrations of Fe(II), Fe(III), Ni(II), Cr(II), Cr(III), Cr(VI), Mn(II), and Mn(III) as functions of and T. Measured liquidus temperature (TL) data for the test glasses within the same range were then added to a critically evaluated TL database composed of multicomponent borosilicate glasses within the spinel primary crystalline phase field. The set of partial molar liquidus temperatures for element other than Oxygen determined from this database was then augmented by values for Fe(II), Fe(III), Cr(II) The oxidation-reduction equilibrium of Fe in a multicomponent borosilicate glass containing several multivalent elements (Fe, Ni, Cr, Mn) and precipitating spinel was measured over a range of imposed oxygen partial pressures ( ) [10-14 Pa to 105 Pa] and temperatures (T) [850 C to 1300 C] with Mössbauer spectroscopy and wet colorimetry. These data were combined with oxidation-reduction equilibria for Fe, Ni, Cr, and Mn in a borosilicate frit of a similar composition found in the literature to estimate concentrations of Fe(II), Fe(III), Ni(II), Cr(II), Cr(III), Cr(VI), Mn(II), and Mn(III) as functions of and T. Measured liquidus temperature (TL) data for the test glasses within the same range were then added to a critically evaluated TL database composed of multicomponent borosilicate glasses within the spinel primary crystalline phase field. The set of partial molar liquidus temperatures for element other than Oxygen determined from this database was then augmented by values for Fe(II), Fe(III), Cr(II) (en)
Title	Partial Molar Liquidus Temperatures of Multivalent Elements in Multicomponent Borosilicate Glass. Partial Molar Liquidus Temperatures of Multivalent Elements in Multicomponent Borosilicate Glass. (en)
skos:prefLabel	Partial Molar Liquidus Temperatures of Multivalent Elements in Multicomponent Borosilicate Glass. Partial Molar Liquidus Temperatures of Multivalent Elements in Multicomponent Borosilicate Glass. (en)
skos:notation	RIV/67985858:_____/02:27020069!RIV/2003/AV0/A27003/N
http://linked.open.../vavai/riv/strany	119;127
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z4072921)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Izák, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	657831
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/02:27020069
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	molar liquids; multivalent elements; glass (en)
http://linked.open.../riv/klicoveSlovo	glass molar liquids multivalent elements
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[131429868D03]
http://linked.open...i/riv/nazevZdroje	Physics and Chemistry Glasses
http://linked.open...in/vavai/riv/obor	CI
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	43
http://linked.open...iv/tvurceVysledku	Izák, Pavel Hrma, P. Thomas, M. L. Vienna, J. D. Irwin, G. M.
http://linked.open...n/vavai/riv/zamer	Theoretical fundamentals of chemical processes: equilibrium and dynamic behavior of multiphase reacting systems
issn	0031-9090
number of pages	9 (xsd:int)

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