About: Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin

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About: Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	In background electrolyte (BGE) with the optimal methanol concentration of 30% (v/v), the ion with NCS group bonded to a cluster boron atom exhibits the strongest interaction with α-cyclodextrin and the highest separation selectivity. Interaction of ions with alkyl or thioalkyl group weakens with the increasing substituent size. The ion with phenyl group exhibits the weakest interaction. Bonding of a group to boron atom weakens the ion interaction with α-cyclodextrin. Second substituent further weakens the interaction with α-cyclodextrin. Separation efficiency is lower at the presence of α-cyclodextrin than at its absence. This separation efficiency loss, amounts up to 90%. In background electrolyte (BGE) with the optimal methanol concentration of 30% (v/v), the ion with NCS group bonded to a cluster boron atom exhibits the strongest interaction with α-cyclodextrin and the highest separation selectivity. Interaction of ions with alkyl or thioalkyl group weakens with the increasing substituent size. The ion with phenyl group exhibits the weakest interaction. Bonding of a group to boron atom weakens the ion interaction with α-cyclodextrin. Second substituent further weakens the interaction with α-cyclodextrin. Separation efficiency is lower at the presence of α-cyclodextrin than at its absence. This separation efficiency loss, amounts up to 90%. (en)
Title	Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin (en)
skos:prefLabel	Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin (en)
skos:notation	RIV/61989592:15310/07:00005814!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(IAA400310613), P(KJB400310705), S, Z(AV0Z40310501), Z(MSM6198959216)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Horáková, Hana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	426410
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/07:00005814
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Capillary electrophoresis; Boron cluster compounds; Chiral separations; Cyclodextrins (en)
http://linked.open.../riv/klicoveSlovo	Capillary electrophoresis Chiral separations Cyclodextrins Boron cluster compounds
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[A3838AEF8CB8]
http://linked.open...i/riv/nazevZdroje	Journal of Chromatography A: Symposium Volumes
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Mass spectrometric and electrophoretic research of boron cluster compounds Investigation of interactions of boron cluster anions with common constituents and special additives of electrophoretic systems.
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	1143
http://linked.open...iv/tvurceVysledku	Horáková, Hana Vespalec, Radim
http://linked.open...n/vavai/riv/zamer	Moderní analytické techniky pro bioanalýzu, ekologii a nanotechnologie Modulation of signalling and regulatory pathways in normal and cancer cells
issn	0021-9673
number of pages	10 (xsd:int)
http://localhost/t...ganizacniJednotka	15310
is http://linked.open...avai/riv/vysledek of	Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin

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