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| Description
| - The development in chemistry of boron cluster compounds requires completing of the research of synthesis with studies supplying knowledge, which stimulate also utilization of synthesized compounds. Mass spectrometry and capillary electrophoresis may serve for this. Cognizance of both fragmentation mechanisms and of influence of experimental conditions on ionization of cluster compounds of various types will allow identification of both ionisable compounds and applicability of mass spectrometry for investigation of weak non-bonding interactions (complexations) of boron compounds. Electrophoretic research will lend first set of systematic knowledge on behavior of various cluster compound types in solution and on their interactions with selected solution constituents. This knowledge will serve for proposal of analytical methods and for interaction studies with tailored compounds including those inhibiting HIV protease. (en)
- Rozvoj chemie boru vyžaduje doplnění výzkumu syntéz navazujícími studiemi, jejichž poznatky budou stimulovat také výzkum využití syntetizovaných sloučenin. K tomu lze využít hmotnostní spektrometrie a kapilární elektroforézy. Znalost fragmentačních mechanismů i vlivu experimentálních podmínek na ionizaci různých typů klastrových sloučenin boru umožní zjistit které sloučeniny lze ionizovat a zda lze hmotnostní spektrometrie využít i ke studiu slabých nevazebných interakcí (komplexací) sloučenin boru. Elektroforetický výzkum poskytne první systematické poznatky o chování různých typů klastrových sloučenin boru v roztocích a o jejich interakcích s vybranými složkami roztoku. Tyto poznatky budou využity k návrhu analytických metod a k interakčním studiím s cíleně syntetizovanými sloučeninami boru včetně těch, které inhibují HIV proteázu.
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| Title
| - Mass spectrometric and electrophoretic research of boron cluster compounds (en)
- Hmotnostně spektrometrický a elektroforetický výzkum klastrových sloučenin boru
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| skos:notation
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| http://linked.open...avai/cep/aktivita
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| http://linked.open...kovaStatniPodpora
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| http://linked.open...ep/celkoveNaklady
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| http://linked.open...datumDodatniDoRIV
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| http://linked.open...i/cep/druhSouteze
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| http://linked.open...ep/duvernostUdaju
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| http://linked.open.../cep/fazeProjektu
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| http://linked.open...ai/cep/hlavniObor
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| http://linked.open...hodnoceniProjektu
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| http://linked.open...vai/cep/kategorie
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| http://linked.open.../cep/klicovaSlova
| - mass spectrometry, capillary electrophoresis, boron cluster compounds (en)
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| http://linked.open...ep/partnetrHlavni
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| http://linked.open...inujicichPrijemcu
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| http://linked.open...cep/pocetPrijemcu
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| http://linked.open...ocetSpoluPrijemcu
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| http://linked.open.../pocetVysledkuRIV
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| http://linked.open...enychVysledkuVRIV
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| http://linked.open...lneniVMinulemRoce
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| http://linked.open.../prideleniPodpory
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| http://linked.open...iciPoslednihoRoku
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| http://linked.open...atUdajeProjZameru
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| http://linked.open.../vavai/cep/soutez
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| http://linked.open...usZobrazovaneFaze
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| http://linked.open...ai/cep/typPojektu
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| http://linked.open...ep/ukonceniReseni
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| http://linked.open.../cep/vedlejsiObor
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| http://linked.open...ep/zahajeniReseni
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| http://linked.open...jektu+dodavatelem
| - Byly studovány možnosti chirální separace substituovaných klastrových sloučenin boru a heteroboranů pomocí kapilární elektroforézy. Byl studován vliv podmínek ionizace a fragmentační mechanismy těchto sloučenin v podmínkách hmotnostní spektrometrie. (cs)
- The possibility of chiral separation of substituted cluster boron coumpounds and heteroboranes using capillary electrophoresis was studied. The influence of ionization conditions and their fragmentation routes in mass spectrometry were evaluated. (en)
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| http://linked.open...tniCyklusProjektu
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| http://linked.open.../cep/klicoveSlovo
| - mass spectrometry
- capillary electrophoresis
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| is http://linked.open...vavai/riv/projekt
of | - Historie hmotnostní spektrometrie
- Cobalt bis(dicarbollide) ions functionalized by CMPO-like groups attached to boron by short bonds; efficient extraction agents for separation of trivalent f-block elements from highly acidic nuclear waste
- Emerging subject for chiral separation science: cluster boron compounds
- Influence of substituents on selectivity and efficiency of chiral separations of anions containing single nido-7,8-dicarbaundecaborane cluster with α-cyclodextrin
- Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes
- Electrophoretic investigation of the boron cluster anion [7-(2-pyridyl)-nido-7,8-dicarbaundecaborate]- and its protonated zwitterionic product
- tert-Butyl-calix[4]arenes Substituted at the Narrow Rim with Cobalt Bis(dicarbollide)(1-) and CMPO Groups - New and Efficient Extractants for Lanthanides and Actinides
- Fragmentation of boron cluster compounds in MS/MS on spherical ion trap
- Application of tandem mass spectrometry on 3D-ion trap for the identification of carboranes
- Historie hmotnostní spektrometrie
- Fragmentační mechanismy při elektronové ionizaci
- Synthesis, Characterization, and UV-vis Linear Absorption of Centrosymmetric Pi-Systems Incorporating closo-Dodecaborate Clusters
- Electrospray Ionization - Ion Trap Mass Spectrometry of Carboranes
- The comparison of chiral separations of boron cluster anoins and organic anions with cyclodextrins
- Synthesis, reactivity and complexation studies of N,S exo-heterodisubstituted o-carborane ligands. Carborane as a platform to produce the uncommon bidentate chelating (pyridine)N-C-C-C-S(H) motif
- Capillary electrophoresis of boron cluster compounds in aqueous and nonaqueous solvents
- Synergistic effect of ligating and ionic functions, prearranged on a calix[4]arene
- Dimethylsulfide-dicarbaborane chemistry. Isolation and characterisation of isomers [9-(SMe2)-nido-7,8-C2B9H10-X-Me] (where X=1, 2, 3 and 4) and some related compounds. An unusual skeletal rearrangement
- 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules
- Synthesis and investigation of the boron cluster anion [7-(2-pyridyl)-7,8-nido-dicarbaundecaborate] and its protonated form
- Identification of boron cluster compounds using spherical ion trap and o-TOF MS instruments
- Application of mass spectrometry on spherical ion trap for the identification of cluster boron compounds
- Fragmentační mechanismy při elektronové ionizaci
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| is http://linked.open...vavai/cep/projekt
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