About: Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)]

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About: Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Five new complexes of composition [Cu(dpt)Ni(CN)(4)] (1) (dpt = dipropylenetriamine), [Cu(dien)Ni(CN)(4)].2H(2)O (2) (dien = diethylenetriamine), [Cu(N,N'-dimeen)Ni(CN)(4)].H2O (3) (N,N' dimeen = N,N'-dimethylethylenediamine), [Cu(N,N dimeen)Ni(CN)(4)].H2O (4) (N,N-dimeen N,N dimethylethylenediamine) and [Cu(trimeen)Ni(CN)(4)] (5) (trimeen=N,N,N'-trimethylethylenediamine) have been obtained by the reactions of the mixture of Cu(ClO4)(2).6H(2)O, appropriate amine and K-2[Ni(CN)(4)] in water and have beencharacterized by IR and UV-Vis spectroscopies and magnetic measurements. The crystal structure of [Cu(dpt)Ni(CN)(4)] (1) has been determined by single-crystal X-ray analysis. The structure of 1 consists of a one-dimensional polymeric chain -Cu(dpt)-NC-N i(CN)(2)-CN Cu(dpt)- in which the Cu(II) and Ni(11) atoms are linked by CN groups. The nickel atom is four coordinate with four cyanide carbon atoms (two cyano groups are terminal and two cyano groups (in cis fashion) are bridged) in a square-planar arra Five new complexes of composition [Cu(dpt)Ni(CN)(4)] (1) (dpt = dipropylenetriamine), [Cu(dien)Ni(CN)(4)].2H(2)O (2) (dien = diethylenetriamine), [Cu(N,N'-dimeen)Ni(CN)(4)].H2O (3) (N,N' dimeen = N,N'-dimethylethylenediamine), [Cu(N,N dimeen)Ni(CN)(4)].H2O (4) (N,N-dimeen N,N dimethylethylenediamine) and [Cu(trimeen)Ni(CN)(4)] (5) (trimeen=N,N,N'-trimethylethylenediamine) have been obtained by the reactions of the mixture of Cu(ClO4)(2).6H(2)O, appropriate amine and K-2[Ni(CN)(4)] in water and have beencharacterized by IR and UV-Vis spectroscopies and magnetic measurements. The crystal structure of [Cu(dpt)Ni(CN)(4)] (1) has been determined by single-crystal X-ray analysis. The structure of 1 consists of a one-dimensional polymeric chain -Cu(dpt)-NC-N i(CN)(2)-CN Cu(dpt)- in which the Cu(II) and Ni(11) atoms are linked by CN groups. The nickel atom is four coordinate with four cyanide carbon atoms (two cyano groups are terminal and two cyano groups (in cis fashion) are bridged) in a square-planar arra (en)
Title	Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)] Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)] (en)
skos:prefLabel	Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)] Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)] (en)
skos:notation	RIV/61989592:15310/01:00001646!RIV/2003/MSM/153103/N
http://linked.open.../vavai/riv/strany	3301-3306
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 153100007)
http://linked.open...iv/cisloPeriodika	28
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Smékal, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	676693
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/01:00001646
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	copper(II) complexes; nickel(II) complexes; cyano-bridged complexes; magnetic properties; crystal structures (en)
http://linked.open.../riv/klicoveSlovo	crystal structures nickel(II) complexes magnetic properties copper(II) complexes cyano-bridged complexes
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[7E646A8A09B2]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	20
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Smékal, Zdeněk Mrozinski, Jerzy
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20153100007
issn	0277-5387
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

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