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rdf:type
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Description
| - Five new complexes of composition [Cu(dpt)Ni(CN)(4)] (1) (dpt = dipropylenetriamine), [Cu(dien)Ni(CN)(4)].2H(2)O (2) (dien = diethylenetriamine), [Cu(N,N'-dimeen)Ni(CN)(4)].H2O (3) (N,N' dimeen = N,N'-dimethylethylenediamine), [Cu(N,N dimeen)Ni(CN)(4)].H2O (4) (N,N-dimeen N,N dimethylethylenediamine) and [Cu(trimeen)Ni(CN)(4)] (5) (trimeen=N,N,N'-trimethylethylenediamine) have been obtained by the reactions of the mixture of Cu(ClO4)(2).6H(2)O, appropriate amine and K-2[Ni(CN)(4)] in water and have beencharacterized by IR and UV-Vis spectroscopies and magnetic measurements. The crystal structure of [Cu(dpt)Ni(CN)(4)] (1) has been determined by single-crystal X-ray analysis. The structure of 1 consists of a one-dimensional polymeric chain -Cu(dpt)-NC-N i(CN)(2)-CN Cu(dpt)- in which the Cu(II) and Ni(11) atoms are linked by CN groups. The nickel atom is four coordinate with four cyanide carbon atoms (two cyano groups are terminal and two cyano groups (in cis fashion) are bridged) in a square-planar arra
- Five new complexes of composition [Cu(dpt)Ni(CN)(4)] (1) (dpt = dipropylenetriamine), [Cu(dien)Ni(CN)(4)].2H(2)O (2) (dien = diethylenetriamine), [Cu(N,N'-dimeen)Ni(CN)(4)].H2O (3) (N,N' dimeen = N,N'-dimethylethylenediamine), [Cu(N,N dimeen)Ni(CN)(4)].H2O (4) (N,N-dimeen N,N dimethylethylenediamine) and [Cu(trimeen)Ni(CN)(4)] (5) (trimeen=N,N,N'-trimethylethylenediamine) have been obtained by the reactions of the mixture of Cu(ClO4)(2).6H(2)O, appropriate amine and K-2[Ni(CN)(4)] in water and have beencharacterized by IR and UV-Vis spectroscopies and magnetic measurements. The crystal structure of [Cu(dpt)Ni(CN)(4)] (1) has been determined by single-crystal X-ray analysis. The structure of 1 consists of a one-dimensional polymeric chain -Cu(dpt)-NC-N i(CN)(2)-CN Cu(dpt)- in which the Cu(II) and Ni(11) atoms are linked by CN groups. The nickel atom is four coordinate with four cyanide carbon atoms (two cyano groups are terminal and two cyano groups (in cis fashion) are bridged) in a square-planar arra (en)
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Title
| - Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)]
- Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)] (en)
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skos:prefLabel
| - Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)]
- Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)] (en)
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skos:notation
| - RIV/61989592:15310/01:00001646!RIV/2003/MSM/153103/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/01:00001646
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - copper(II) complexes; nickel(II) complexes; cyano-bridged complexes; magnetic properties; crystal structures (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Císařová, Ivana
- Smékal, Zdeněk
- Mrozinski, Jerzy
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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