About: Preparation, physicochemical properties and biological activity of copper(II) complexes with 6-(2-chlorbenzylamino)purine (HL1) or 6-(3-chlorbenzylamino)purine (HL2). The single-crystal X-ray structure of [Cu(H(+)L2]2Cl3]Cl.2H2O

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About: Preparation, physicochemical properties and biological activity of copper(II) complexes with 6-(2-chlorbenzylamino)purine (HL1) or 6-(3-chlorbenzylamino)purine (HL2). The single-crystal X-ray structure of [Cu(H(+)L2]2Cl3]Cl.2H2O Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A series of mononuclear Cu(II), Pd(II) and Pt(II) complexes with selected 6-benzylaminopurine derivatives, namely 6-(2-hydroxybenzylamino)purine 2OHBAP, 6-(3-fluorobenzylamino)purine 3FBAP, 2-(3-hydroxypropylamino)-6-benzylamino-9-isopropylpurine BOH and2-(2-hydroxyethylamino)-6-benzylamino-9-metylpurine OLO, has been synthesized and characterized by elemental analysis, electronic, infrared and mass (FAB+, ESI+) spectral data, magnetic susceptibility and molar conductivity data. On the basis of data re sulting mainly from a single crystal X-ray analysis, a composition of the prepared complexes is following: [CuCl3(2OHBAP+)2]Cl.2H2O, [CuCl3(3FBAP+)2]Cl.H2O, [PdCl3(BOH+)].H2O, [PdCl3(OLO+)].H2O, [PtCl3(BOH+)].H2O, [PtCl3(OLO+)].H2O. Cytotoxic activity of the complexes as well as the starting compounds was determined by a calcein AM assay on various human tumor cell lines. A series of mononuclear Cu(II), Pd(II) and Pt(II) complexes with selected 6-benzylaminopurine derivatives, namely 6-(2-hydroxybenzylamino)purine 2OHBAP, 6-(3-fluorobenzylamino)purine 3FBAP, 2-(3-hydroxypropylamino)-6-benzylamino-9-isopropylpurine BOH and2-(2-hydroxyethylamino)-6-benzylamino-9-metylpurine OLO, has been synthesized and characterized by elemental analysis, electronic, infrared and mass (FAB+, ESI+) spectral data, magnetic susceptibility and molar conductivity data. On the basis of data re sulting mainly from a single crystal X-ray analysis, a composition of the prepared complexes is following: [CuCl3(2OHBAP+)2]Cl.2H2O, [CuCl3(3FBAP+)2]Cl.H2O, [PdCl3(BOH+)].H2O, [PdCl3(OLO+)].H2O, [PtCl3(BOH+)].H2O, [PtCl3(OLO+)].H2O. Cytotoxic activity of the complexes as well as the starting compounds was determined by a calcein AM assay on various human tumor cell lines. (en)
Title	Preparation, physicochemical properties and biological activity of copper(II) complexes with 6-(2-chlorbenzylamino)purine (HL1) or 6-(3-chlorbenzylamino)purine (HL2). The single-crystal X-ray structure of [Cu(H(+)L2]2Cl3]Cl.2H2O Preparation, physicochemical properties and biological activity of copper(II) complexes with 6-(2-chlorbenzylamino)purine (HL1) or 6-(3-chlorbenzylamino)purine (HL2). The single-crystal X-ray structure of [Cu(H(+)L2]2Cl3]Cl.2H2O (en)
skos:prefLabel	Preparation, physicochemical properties and biological activity of copper(II) complexes with 6-(2-chlorbenzylamino)purine (HL1) or 6-(3-chlorbenzylamino)purine (HL2). The single-crystal X-ray structure of [Cu(H(+)L2]2Cl3]Cl.2H2O Preparation, physicochemical properties and biological activity of copper(II) complexes with 6-(2-chlorbenzylamino)purine (HL1) or 6-(3-chlorbenzylamino)purine (HL2). The single-crystal X-ray structure of [Cu(H(+)L2]2Cl3]Cl.2H2O (en)
skos:notation	RIV/61989592:15310/01:00001268!RIV/2002/GA0/153102/N
http://linked.open.../vavai/riv/strany	23-32
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/00/0152), P(VS96154), Z(MSM 153100008)
http://linked.open...iv/cisloPeriodika	N
http://linked.open...vai/riv/dodaniDat	2002
http://linked.open...aciTvurceVysledku	Doležal, Karel Strnad, Miroslav Trávníček, Zdeněk Šindelář, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	692563
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/01:00001268
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	physicochemical properties (en)
http://linked.open.../riv/klicoveSlovo	physicochemical properties
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[450C6350DFD5]
http://linked.open...i/riv/nazevZdroje	Journal of Inorganic Biochemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Synthesis, study and biology activity of coordination compounds of selected transition metals with purine derivatives Profilation of the centrum of molecular and cellular biology and medicine of the Palacký University (CMBM UP). Research program and infrastructure
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	84
http://linked.open...iv/tvurceVysledku	Doležal, Karel Strnad, Miroslav Trávníček, Zdeněk Marek, J. Šindelář, Zdeněk Kryštof, V. Maloň, M. Rolčík, J.
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20153100008
issn	0162-0134
number of pages	10 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

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