About: Interaction of cesium ions with calix[4]arene-bis(t-octylbenzo-18-crown-6): NMR and theoretical study

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About: Interaction of cesium ions with calix[4]arene-bis(t-octylbenzo-18-crown-6): NMR and theoretical study Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Interaction of cesium dicarbollylcobaltate with calix[4]arene-bis(t-octylbenzo-18-crown-6) in nitrobenzene-d5 was studied using 1H, 13C, and 133Cs NMR, relaxations and PFG NMR. It was found that the calixarene-bis-crown binds two Cs cations with almost equal strength. Diffusion measurements and DFT calculations show that one DCC anion is bound to the complex. The dynamics of Cs binding was studied by a saturation-transfer technique. Interaction of cesium dicarbollylcobaltate with calix[4]arene-bis(t-octylbenzo-18-crown-6) in nitrobenzene-d5 was studied using 1H, 13C, and 133Cs NMR, relaxations and PFG NMR. It was found that the calixarene-bis-crown binds two Cs cations with almost equal strength. Diffusion measurements and DFT calculations show that one DCC anion is bound to the complex. The dynamics of Cs binding was studied by a saturation-transfer technique. (en)
Title	Interaction of cesium ions with calix[4]arene-bis(t-octylbenzo-18-crown-6): NMR and theoretical study Interaction of cesium ions with calix[4]arene-bis(t-octylbenzo-18-crown-6): NMR and theoretical study (en)
skos:prefLabel	Interaction of cesium ions with calix[4]arene-bis(t-octylbenzo-18-crown-6): NMR and theoretical study Interaction of cesium ions with calix[4]arene-bis(t-octylbenzo-18-crown-6): NMR and theoretical study (en)
skos:notation	RIV/61389013:_____/11:00360502!RIV12-AV0-61389013
http://linked.open...avai/predkladatel	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(GA203/09/1478), S, Z(AV0Z4050913), Z(MSM4977751303)
http://linked.open...iv/cisloPeriodika	23
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Dybal, Jiří Kříž, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	205230
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/11:00360502
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	calixaren-bis-crown; cesium ions; NMR (en)
http://linked.open.../riv/klicoveSlovo	calixaren-bis-crown cesium ions NMR
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[23B4D5D9FBFA]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry B
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Poloxamers and their modification – micelisation and gelation mechanism
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	115
http://linked.open...iv/tvurceVysledku	Dybal, Jiří Kříž, Jaroslav Makrlík, E. Vaňura, P. Moyer, B. A.
http://linked.open...ain/vavai/riv/wos	000291338900010
http://linked.open...n/vavai/riv/zamer	Cílená syntéza a studium chemických, fyzikálně-chemických a fyzikálních vlastností makromolekulárních a nadmolekulárních látek a soustav pro vyspělé technologie Predikce poruch heterogenních materiálů, komponent mechanických a biomechanických systémů.
issn	1520-6106
number of pages	10 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/jp203221k
is http://linked.open...avai/riv/vysledek of	Interaction of cesium ions with calix[4]arene-bis(t-octylbenzo-18-crown-6): NMR and theoretical study Interaction of cesium ions with calix[4]arene-bis(t-octylbenzo-18-crown-6): NMR and theoretical study

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