About: Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Radical polymerization of selected 1-alkenes, (1-hexene, 1-octene and 2-methyl-1-heptene), initiated with classical radical initiators and catalyzed by lithium salts of selected carboranes was studied. In accordance with recently published results it was found that the use of radical initiators under catalysis by %22naked'' lithium cation of carboranes promotes the radical polymerization of 1-alkenes, otherwise nonpolymerizable by the radical mechanism. However, although in our experiments relatively high monomers conversions are reached for some of the thermal initiators used, only low-molecular-weight oligomers with M-n < 1000 are formed, regardless of the initiator and carborane anion used. Radical polymerization of selected 1-alkenes, (1-hexene, 1-octene and 2-methyl-1-heptene), initiated with classical radical initiators and catalyzed by lithium salts of selected carboranes was studied. In accordance with recently published results it was found that the use of radical initiators under catalysis by %22naked'' lithium cation of carboranes promotes the radical polymerization of 1-alkenes, otherwise nonpolymerizable by the radical mechanism. However, although in our experiments relatively high monomers conversions are reached for some of the thermal initiators used, only low-molecular-weight oligomers with M-n < 1000 are formed, regardless of the initiator and carborane anion used. (en)
Title	Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes (en)
skos:prefLabel	Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes (en)
skos:notation	RIV/61389013:_____/11:00359127!RIV12-AV0-61389013
http://linked.open...avai/predkladatel	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(ME09001), Z(AV0Z40500505), Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Vlček, Petr Látalová, Petra Janata, Miroslav Svitáková, Romana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	225554
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/11:00359127
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	1-alkenes; carborane anion; oligomers (en)
http://linked.open.../riv/klicoveSlovo	oligomers 1-alkenes carborane anion
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[BA7A01046B75]
http://linked.open...i/riv/nazevZdroje	Journal of Polymer Science. Part A - Polymer Chemistry
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...vavai/riv/projekt	Radical polymerization of 1-alkenes promoted with Li salts of monocarbadodecaborates
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	49
http://linked.open...iv/tvurceVysledku	Janata, Miroslav Kaleta, Jiří Látalová, Petra Michl, Josef Vlček, Petr Valášek, Michal Volkis, V. Svitáková, Romana
http://linked.open...ain/vavai/riv/wos	000288966600010
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství
issn	0887-624X
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/pola.24629
is http://linked.open...avai/riv/vysledek of	Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes Radical polymerization of 1-alkenes catalyzed by lithium salts of carboranes

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