About: Synthesis and properties of cationic polyelectrolyte with regioregular polyalkylthiophene backbone and ionic-liquid like side groups

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Description	High-regioregular poly{3-[6-(1-methylimidazolium-3-yl)hexyl]thiophene-2,5-diyl bromide}, PMHT-Br, has been prepared by reaction of high-regioregular (above 92%) poly[3-(6-bromohexyl)thiophene-2,5-diyl] with 1-methylimidazole. PMHT-Br is soluble in water and water miscible solvents such as methanol, DMSO and shows solvatochromism; lambda(max) (nm): 423 (H2O); 435 (MeOH); 452 (DMSO). Increased absorption band broadening observed for aqueous solution as well as NMR spectra in 020 suggests a micelle-like structure of PMHT-Br molecules in these solutions: poly(3-hexylthiophene) core and 1-methylimidazolium bromide shell. Despite the disturbing effect of ionic groups, the solid-state PMHT-Br shows absorption maximum at 520 nm, the band edge at 660 nm (ca. 1.9 eV), and fluorescence emission with maximum at 635 nm, in a good agreement with the polymer regioregularity. High-regioregular poly{3-[6-(1-methylimidazolium-3-yl)hexyl]thiophene-2,5-diyl bromide}, PMHT-Br, has been prepared by reaction of high-regioregular (above 92%) poly[3-(6-bromohexyl)thiophene-2,5-diyl] with 1-methylimidazole. PMHT-Br is soluble in water and water miscible solvents such as methanol, DMSO and shows solvatochromism; lambda(max) (nm): 423 (H2O); 435 (MeOH); 452 (DMSO). Increased absorption band broadening observed for aqueous solution as well as NMR spectra in 020 suggests a micelle-like structure of PMHT-Br molecules in these solutions: poly(3-hexylthiophene) core and 1-methylimidazolium bromide shell. Despite the disturbing effect of ionic groups, the solid-state PMHT-Br shows absorption maximum at 520 nm, the band edge at 660 nm (ca. 1.9 eV), and fluorescence emission with maximum at 635 nm, in a good agreement with the polymer regioregularity. (en)
Title	Synthesis and properties of cationic polyelectrolyte with regioregular polyalkylthiophene backbone and ionic-liquid like side groups Synthesis and properties of cationic polyelectrolyte with regioregular polyalkylthiophene backbone and ionic-liquid like side groups (en)
skos:prefLabel	Synthesis and properties of cationic polyelectrolyte with regioregular polyalkylthiophene backbone and ionic-liquid like side groups Synthesis and properties of cationic polyelectrolyte with regioregular polyalkylthiophene backbone and ionic-liquid like side groups (en)
skos:notation	RIV/61389013:_____/10:00345579!RIV11-AV0-61389013
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(GA104/09/1435), P(GD203/08/H032), P(KAN100500652), S, Z(AV0Z40500505), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	14
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Pfleger, Jiří Sharf, Ahmed
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	291490
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/10:00345579
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	conjugated polymers; ionic polythiophene; optical properties (en)
http://linked.open.../riv/klicoveSlovo	ionic polythiophene conjugated polymers optical properties
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[4C138D79DA7F]
http://linked.open...i/riv/nazevZdroje	Journal of Polymer Science. Part A - Polymer Chemistry
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Advanced catalytic processes for preparation of organic photoelectronic materials Advanced catalytic processes and materials Heterogeneous and hybrid nanocomposite materials for solar cells
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	48
http://linked.open...iv/tvurceVysledku	Pfleger, Jiří Procházka, M. Vohlídal, J. Bondarev, D. Sharf, Ahmed Zedník, J. Šloufová, I.
http://linked.open...ain/vavai/riv/wos	000279707300011
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0887-624X
number of pages	9 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Synthesis and properties of cationic polyelectrolyte with regioregular polyalkylthiophene backbone and ionic-liquid like side groups Synthesis and properties of cationic polyelectrolyte with regioregular polyalkylthiophene backbone and ionic-liquid like side groups Synthesis and properties of cationic polyelectrolyte with regioregular polyalkylthiophene backbone and ionic-liquid like side groups

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