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rdf:type
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Description
| - Novel and more convenient synthetic route for the thiocyanation of B12 H12 2- is presented in which /in situ /generated thiocyanogen (SCN)2 is used as the reagent. The synthesized disubstituted product B12 H10 (SCN)2 -2- is exclusively the /meta/ positional isomer as confirmed by the X-ray crystallographic analysis. The quantum chemical calculations yielded a clear and consistent picture of the electrophilic substitution (S-E ) reaction mechanism of the thiocyanation of B12H12 2- , thus broadening our understanding of boron hydride reactivity.
- Novel and more convenient synthetic route for the thiocyanation of B12 H12 2- is presented in which /in situ /generated thiocyanogen (SCN)2 is used as the reagent. The synthesized disubstituted product B12 H10 (SCN)2 -2- is exclusively the /meta/ positional isomer as confirmed by the X-ray crystallographic analysis. The quantum chemical calculations yielded a clear and consistent picture of the electrophilic substitution (S-E ) reaction mechanism of the thiocyanation of B12H12 2- , thus broadening our understanding of boron hydride reactivity. (en)
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Title
| - Thiocyanation of closo-Dodecaborate B12H12 2-. A Novel Synthetic Route and Theoretical Elucidation of the Reaction Mechanism
- Thiocyanation of closo-Dodecaborate B12H12 2-. A Novel Synthetic Route and Theoretical Elucidation of the Reaction Mechanism (en)
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skos:prefLabel
| - Thiocyanation of closo-Dodecaborate B12H12 2-. A Novel Synthetic Route and Theoretical Elucidation of the Reaction Mechanism
- Thiocyanation of closo-Dodecaborate B12H12 2-. A Novel Synthetic Route and Theoretical Elucidation of the Reaction Mechanism (en)
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skos:notation
| - RIV/61388980:_____/10:00346285!RIV11-MSM-61388980
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(IAAX00320901), P(LC512), P(LC523), Z(AV0Z40320502), Z(AV0Z40550506)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/10:00346285
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - thiocyanation; closo-dodecaborate; reaction mechanism; theoretical calculations (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Buděšínský, Miloš
- Grüner, Bohumír
- Lepšík, Martin
- Plešek, Jaromír
- Rulíšek, Lubomír
- Klepetářová, Blanka
- Hnyk, Drahomír
- Srnec, Martin
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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is http://linked.open...avai/riv/vysledek
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