About: Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Vodorozpustné 2,7-disulfonato-9,10-diphenylanthracene (2,7-dsDPA) and 2,6-disulfonato-9,10-diphenylanthracene (2,6-dsDPA) reagují se singletovým kyslíkem 1O2 produkovaným a tvoří termostabilní endoperoxidy.Thermální dekompozice endoperoxidů za vyšších teplot vede ke tvorbě 1O2. 2,7-dsDPA, 2,6-dsDPA a odpovídající endoperoxidy 2,7-dsDPAO2, 2,6-dsDPAO2 tvoří 1:1 host–guest komplexy s nativními cyklodextriny (CDs) a hydroxypropylovanými cyklodextriny (hpCDs). Vazebné konstanty závisejí na velikosti kavity a funkcionalizaci primary face CDs. Termální stability obou endoperoxidů v host–guest komplexech s CDs a hpCDs rostou. (cs) Water-soluble 2,7-disulfonato-9,10-diphenylanthracene (2,7-dsDPA) and 2,6-disulfonato-9,10-diphenylanthracene (2,6-dsDPA) react with singlet oxygen O2produced by photosensitized reaction and form thermostable endoperoxides. The thermal decomposition of endoperoxides at higher temperatures leads to the production of O2. 2,7-dsDPA, 2,6-dsDPA and corresponding endoperoxides 2,7-dsDPAO2, 2,6-dsDPAO2 form 1:1 host–guest complexes with native cyclodextrins and 2-hydroxypropylated cyclodextrins. The binding constants depend on the cavity size and the functionalization of the primary face of CDs. The thermal stabilities of both endoperoxides in host–guest complexes with CDs and hpCDs are highly increased. Water-soluble 2,7-disulfonato-9,10-diphenylanthracene (2,7-dsDPA) and 2,6-disulfonato-9,10-diphenylanthracene (2,6-dsDPA) react with singlet oxygen O2produced by photosensitized reaction and form thermostable endoperoxides. The thermal decomposition of endoperoxides at higher temperatures leads to the production of O2. 2,7-dsDPA, 2,6-dsDPA and corresponding endoperoxides 2,7-dsDPAO2, 2,6-dsDPAO2 form 1:1 host–guest complexes with native cyclodextrins and 2-hydroxypropylated cyclodextrins. The binding constants depend on the cavity size and the functionalization of the primary face of CDs. The thermal stabilities of both endoperoxides in host–guest complexes with CDs and hpCDs are highly increased. (en)
Title	Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and Supramolekulární nosiče singletového kyslíku: Fotosenzitivní tvorba a termální dekompozice endoperoxidů v přítomnosti cyklodextrinů (cs) Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and (en)
skos:prefLabel	Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and Supramolekulární nosiče singletového kyslíku: Fotosenzitivní tvorba a termální dekompozice endoperoxidů v přítomnosti cyklodextrinů (cs) Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and (en)
skos:notation	RIV/61388980:_____/08:00309320!RIV09-AV0-61388980
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/06/1244), P(GA203/07/1424), Z(AV0Z40320502), Z(AV0Z40400503), Z(AV0Z40720504), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Mosinger, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	398402
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/08:00309320
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	singlet oxygen; diphenylanthracene endoperoxides; cyclodextrins (en)
http://linked.open.../riv/klicoveSlovo	diphenylanthracene endoperoxides singlet oxygen cyclodextrins
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[044C794281BC]
http://linked.open...i/riv/nazevZdroje	Journal of Photochemistry and Photobiology A-Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Singlet oxygen producing sensitizers on solid inorganic hosts: photodisinfecting materials and probes Self-assembled porphyrin nanostructures
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	195
http://linked.open...iv/tvurceVysledku	Kubát, Pavel Mosinger, Jiří Slavětínská, Lenka
http://linked.open...ain/vavai/riv/wos	254324600001
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Investigation of multiphase reacting systems for the design of processes important in synthesis and preparation of novel materials, in energy production and in environmental protection Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1010-6030
number of pages	9 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and Supramolecular Carriers of Singlet Oxygen: Photosensitized Formation and

Faceted Search & Find service v1.16.116 as of Feb 22 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3239 as of Feb 22 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 80 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software