About: Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)(2)] to give [(PMe2Ph)(2)PtB16H17Me] and [(PMe2Ph)(2)PtB14H16]

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About: Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)(2)] to give [(PMe2Ph)(2)PtB16H17Me] and [(PMe2Ph)(2)PtB14H16] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Structurally characterised 17-vertex [(PMe2Ph)(2)PtB16H17Me] 3 is obtained, albeit in low yield, by platination of 16-vertex B16H20 1 using [PtMe2(PMe2Ph)(2)] under mild conditions. Platination has occurred on the {B-10} subcluster of 1, interesting in that B16H20 itself deprotonates on the {B-8} subcluster: the reference 16-vertex [B16H19](-) anion 1a, prepared by deprotonation of 1 with 1,8-bis(dimethylamino) naphthalene, is also structurally characterised. [PtMe2(PMe2Ph)(2)] with 14-vertex B14H18 2 similarly gives a low yield of 15-vertex [(PMe2Ph)(2)PtB14H16] 5, of formulation and structure substantiated by DFT calculations. Structurally characterised 17-vertex [(PMe2Ph)(2)PtB16H17Me] 3 is obtained, albeit in low yield, by platination of 16-vertex B16H20 1 using [PtMe2(PMe2Ph)(2)] under mild conditions. Platination has occurred on the {B-10} subcluster of 1, interesting in that B16H20 itself deprotonates on the {B-8} subcluster: the reference 16-vertex [B16H19](-) anion 1a, prepared by deprotonation of 1 with 1,8-bis(dimethylamino) naphthalene, is also structurally characterised. [PtMe2(PMe2Ph)(2)] with 14-vertex B14H18 2 similarly gives a low yield of 15-vertex [(PMe2Ph)(2)PtB14H16] 5, of formulation and structure substantiated by DFT calculations. (en) Byly strukturně charakterisovány nové 17- a 15-vrcholové komplexy platiny, [(PMe2Ph)2PtB16H17Me] a [(PMe2Ph)2PtB14H18] . (cs)
Title	Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)(2)] to give [(PMe2Ph)(2)PtB16H17Me] and [(PMe2Ph)(2)PtB14H16] Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)(2)] to give [(PMe2Ph)(2)PtB16H17Me] and [(PMe2Ph)(2)PtB14H16] (en) Makropolyedrická klastrová borová chemie. Reaction B16H20 a B14H18 s [PtMe2(PMe2Ph)2] za vzniku [(PMe2Ph)2PtB16H17Me] a [(PMe2Ph)2PtB14H16] (cs)
skos:prefLabel	Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)(2)] to give [(PMe2Ph)(2)PtB16H17Me] and [(PMe2Ph)(2)PtB14H16] Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)(2)] to give [(PMe2Ph)(2)PtB16H17Me] and [(PMe2Ph)(2)PtB14H16] (en) Makropolyedrická klastrová borová chemie. Reaction B16H20 a B14H18 s [PtMe2(PMe2Ph)2] za vzniku [(PMe2Ph)2PtB16H17Me] a [(PMe2Ph)2PtB14H16] (cs)
skos:notation	RIV/61388980:_____/05:00029309!RIV06-AV0-61388980
http://linked.open.../vavai/riv/strany	1499;1503
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/05/2646), P(IAA4032701), P(LC523), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Jelínek, Tomáš Štíbr, Bohumil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	528569
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/05:00029309
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	magnetic-resonance spectroscopy; metallaborane clusters (en)
http://linked.open.../riv/klicoveSlovo	magnetic-resonance spectroscopy metallaborane clusters
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[102F8C259BB7]
http://linked.open...i/riv/nazevZdroje	Dalton Transactions: an international journal of inorganic chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Derivatization of ferratricarbollide Fused-Cage Macropolyhedra Boranes, Carboranes, Heteroboranes, and Metallaheteroboranes.
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	-
http://linked.open...iv/tvurceVysledku	Jelínek, Tomáš Štíbr, Bohumil Kennedy, D. J. Thornton-Pett, M. Hursthouse, M. B. Bould, J. Barrett, S. A. Coles, S. J.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	1477-9226
number of pages	5 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)(2)] to give [(PMe2Ph)(2)PtB16H17Me] and [(PMe2Ph)(2)PtB14H16]

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