About: Metal complexes with an amino substituted tricarbollide ligand

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Description	The reaction of the tricarbollide salt Tl[7-tBuNH-7,8,9-C3B8H10] (Tl1) with [(cod)Rh(THF)(x)](+) gives the rhodium complex [1(cod)-12-tBuNH-1,2,4,12-RhC3B8H10] in almost quantitative yield. Analogous reactions of Tl1 with [(ring)M(THF)(x)](2+) ((ring)M = CpRh and (1,3,5-C6H3Me3)Ru) afford the corresponding metallatricarbollides [1-(ring)-12-tBuNH-1,2,4,12-MC3B8H10] in ca. 50% yield. Refluxing Tl1 with [Mn(CO)(3)(MeCN)(3)](+) in THF give the tricarbollide analogue of eymantrene, [1,1,1-(CO)(3)-12-tBuNH-1,2,4,12-MnC3B8H10], the structure of which was determined by single-crystal X-ray diffraction analysis. In all cases, the formation of the metallatricarbollide complexes is accompanied by polyhedral rearrangement leading to the maximum separation of the cage carbon atoms. The reaction of the tricarbollide salt Tl[7-tBuNH-7,8,9-C3B8H10] (Tl1) with [(cod)Rh(THF)(x)](+) gives the rhodium complex [1(cod)-12-tBuNH-1,2,4,12-RhC3B8H10] in almost quantitative yield. Analogous reactions of Tl1 with [(ring)M(THF)(x)](2+) ((ring)M = CpRh and (1,3,5-C6H3Me3)Ru) afford the corresponding metallatricarbollides [1-(ring)-12-tBuNH-1,2,4,12-MC3B8H10] in ca. 50% yield. Refluxing Tl1 with [Mn(CO)(3)(MeCN)(3)](+) in THF give the tricarbollide analogue of eymantrene, [1,1,1-(CO)(3)-12-tBuNH-1,2,4,12-MnC3B8H10], the structure of which was determined by single-crystal X-ray diffraction analysis. In all cases, the formation of the metallatricarbollide complexes is accompanied by polyhedral rearrangement leading to the maximum separation of the cage carbon atoms. (en) Reakce of the trikarbollidové sloučeniny Tl[7-tBuNH-7,8,9-C3B8H10] s různými organokovovými kationty vedla k serii nových trikarbollidových komplexů obsahujících Rh, Ru a Mn jako centrální kovový atom. (cs)
Title	Metal complexes with an amino substituted tricarbollide ligand Metal complexes with an amino substituted tricarbollide ligand (en) Kovové komplexy s aminosubstituovanými tricarbollidovými ligandy (cs)
skos:prefLabel	Metal complexes with an amino substituted tricarbollide ligand Metal complexes with an amino substituted tricarbollide ligand (en) Kovové komplexy s aminosubstituovanými tricarbollidovými ligandy (cs)
skos:notation	RIV/61388980:_____/05:00021493!RIV06-AV0-61388980
http://linked.open.../vavai/riv/strany	2775;2779
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/05/2646), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Holub, Josef Štíbr, Bohumil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	529652
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/05:00021493
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	boron; metallacarboranes; tricarbollide (en)
http://linked.open.../riv/klicoveSlovo	tricarbollide metallacarboranes boron
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[FF2724DAD14D]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Derivatization of ferratricarbollide
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	690
http://linked.open...iv/tvurceVysledku	Holub, Josef Štíbr, Bohumil Kudinov, A. R. Petrovskii, P. V. Perekalin, D. S. Lyssenko, K. A.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	0022-328X
number of pages	5 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Metal complexes with an amino substituted tricarbollide ligand

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