About: 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds     Goto   Sponge   NotDistinct   Permalink

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Description
  • Tetraethyl fluoromethylenebisphosphonate in the presence of cesium carbonate in DMF undergoes efficient 1,4-addition to Michael acceptors having terminal double bond such as alpha,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding adducts (alpha-alkyl-alfa-fluoromethylenebisphosphonates) in good to excellent yields.
  • Tetraethyl fluoromethylenebisphosphonate in the presence of cesium carbonate in DMF undergoes efficient 1,4-addition to Michael acceptors having terminal double bond such as alpha,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding adducts (alpha-alkyl-alfa-fluoromethylenebisphosphonates) in good to excellent yields. (en)
Title
  • 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds
  • 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds (en)
skos:prefLabel
  • 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds
  • 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds (en)
skos:notation
  • RIV/61388963:_____/11:00360880!RIV12-AV0-61388963
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GP203/08/P310), Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 243935
http://linked.open...ai/riv/idVysledku
  • RIV/61388963:_____/11:00360880
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • 1,4-addition; phosphonates; fluorine (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [6E9D4C309617]
http://linked.open...i/riv/nazevZdroje
  • Journal of Fluorine Chemistry
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http://linked.open...v/svazekPeriodika
  • 132
http://linked.open...iv/tvurceVysledku
  • Beier, Petr
  • Opekar, Stanislav
http://linked.open...ain/vavai/riv/wos
  • 000291286000009
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-1139
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jfluchem.2011.03.011
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