Electrospray ionization of dilute methanolic solutions of nickel(II) salts and 1,1’-bis-2-naphthol (BINOL) with secondary alkanols leads to [(BINOLato)Ni(CH3CH(OH)R)]+ cations of which the complex with R = C6H5 shows a significant chiral effect in the gas phase.
Electrospray ionization of dilute methanolic solutions of nickel(II) salts and 1,1’-bis-2-naphthol (BINOL) with secondary alkanols leads to [(BINOLato)Ni(CH3CH(OH)R)]+ cations of which the complex with R = C6H5 shows a significant chiral effect in the gas phase. (en)
Elektrospray ionizace zředěných roztoků nikelnatých (II) solí a 1,1’-bis-2-naftolu (BINOL) se sekundárními alkoholy v metanolu vede ke vzniku [(BINOLáto)Ni(CH3CH(OH)R)]+ kationtů, u jejichž komplexu s R = C6H5 pozorujeme v plynné fázi signifikantní chirální efekt. (cs)