About: The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion

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About: The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Electrospray ionization of a methanolic solution of Michler’s hydrol blue, bis(4-(N,N-dimethylamino)phenyl)methyl tetrafluoroborate, 1+BF4–, produces the formal methanol adduct [1+ .CH3OH], which shows an unusual gas-phase chemistry. The results also question the otherwise successful kinetic method. Electrospray ionization of a methanolic solution of Michler’s hydrol blue, bis(4-(N,N-dimethylamino)phenyl)methyl tetrafluoroborate, 1+BF4–, produces the formal methanol adduct [1+ .CH3OH], which shows an unusual gas-phase chemistry. The results also question the otherwise successful kinetic method. (en) Ionizace elektrosprejem methanolového roztoku Michlerovy modři, bis(4-(N,N-dimethylamino)fenyl)methyl tetrafluoroborate, 1+BF4–, poskytuje formální methanolový adukt [1+ .CH3OH], jež má neobvyklou chemii v plynné fázi. Výsledky také zpochybňují jinak úspěšnou kinetickou metodu. (cs)
Title	The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion (en) Neočekávaná reaktivity CH3OH aduktu Michlerovy hydrolové modři v plynné fázi: katalýza přenosem protonu a postupná eliminace radikálů (cs)
skos:prefLabel	The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion (en) Neočekávaná reaktivity CH3OH aduktu Michlerovy hydrolové modři v plynné fázi: katalýza přenosem protonu a postupná eliminace radikálů (cs)
skos:notation	RIV/61388963:_____/07:00089489!RIV08-AV0-61388963
http://linked.open.../vavai/riv/strany	8925;8933
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika	37
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Roithová, Jana Schröder, Detlef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	456605
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/07:00089489
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	carbenium ions; electrospray ionization; mass spectrometry; proton transfer (en)
http://linked.open.../riv/klicoveSlovo	electrospray ionization mass spectrometry proton transfer carbenium ions
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[0A09CBC3C76A]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry A
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	111
http://linked.open...iv/tvurceVysledku	Schröder, Detlef Schwarz, H. Roithová, Jana Gruene, P. Koszinowski, K. Mayr, H.
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství
issn	1089-5639
number of pages	9 (xsd:int)
is http://linked.open...avai/riv/vysledek of	The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion

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