About: Dynamics of Formation of Products D2CN+, DCN+, and CD3+ in the Reaction of N+ with CD4: A Crossed-Beam and Theoretical Study

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The formation of D2CN+ in the reaction of N+ (P-3) with CD4 was studied using the crossed beam technique at collision energies of 3.66 and 4.86 eV. The experiments were complemented by calculations of stationary points on the triplet hypersurface of the system. The scattering data showed that the reaction proceeds by the formation of two intermediate complexes having different lifetimes: it long-lived statistical intermediate and short-lived complex (mean lifetime about one period of an average rotation) with more energy in translation than the statistical complex. Comparison with theoretical Calculations suggests that the long-lived complex leads the CDND+ isomer of the product ion, whereas the short-lived complex leads prevailingly to the CD2N+ isomer. The product DCN+ results from further decomposition of the primary product D2CN+, whereas CD3+ is formed both by a hydride-ion transfer and it long-lived complex decomposition. The formation of D2CN+ in the reaction of N+ (P-3) with CD4 was studied using the crossed beam technique at collision energies of 3.66 and 4.86 eV. The experiments were complemented by calculations of stationary points on the triplet hypersurface of the system. The scattering data showed that the reaction proceeds by the formation of two intermediate complexes having different lifetimes: it long-lived statistical intermediate and short-lived complex (mean lifetime about one period of an average rotation) with more energy in translation than the statistical complex. Comparison with theoretical Calculations suggests that the long-lived complex leads the CDND+ isomer of the product ion, whereas the short-lived complex leads prevailingly to the CD2N+ isomer. The product DCN+ results from further decomposition of the primary product D2CN+, whereas CD3+ is formed both by a hydride-ion transfer and it long-lived complex decomposition. (en)
Title	Dynamics of Formation of Products D2CN+, DCN+, and CD3+ in the Reaction of N+ with CD4: A Crossed-Beam and Theoretical Study Dynamics of Formation of Products D2CN+, DCN+, and CD3+ in the Reaction of N+ with CD4: A Crossed-Beam and Theoretical Study (en)
skos:prefLabel	Dynamics of Formation of Products D2CN+, DCN+, and CD3+ in the Reaction of N+ with CD4: A Crossed-Beam and Theoretical Study Dynamics of Formation of Products D2CN+, DCN+, and CD3+ in the Reaction of N+ with CD4: A Crossed-Beam and Theoretical Study (en)
skos:notation	RIV/61388955:_____/10:00341545!RIV11-AV0-61388955
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(IAA400400702), S, Z(AV0Z40400503), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Španěl, Patrik Žabka, Ján Herman, Zdeněk Roithová, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	255568
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/10:00341545
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ion-molecule reaction; scattering; density (en)
http://linked.open.../riv/klicoveSlovo	ion-molecule reaction scattering density
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[CECA6485A7D0]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry A
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Investigation of ion-molecule collision processes relevant to the atmosphere of Titan
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	114
http://linked.open...iv/tvurceVysledku	Španěl, Patrik Žabka, Ján Herman, Zdeněk Roithová, Jana
http://linked.open...ain/vavai/riv/wos	000273672600021
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1089-5639
number of pages	8 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Dynamics of Formation of Products D2CN+, DCN+, and CD3+ in the Reaction of N+ with CD4: A Crossed-Beam and Theoretical Study Dynamics of Formation of Products D2CN+, DCN+, and CD3+ in the Reaction of N+ with CD4: A Crossed-Beam and Theoretical Study Dynamics of Formation of Products D2CN+, DCN+, and CD3+ in the Reaction of N+ with CD4: A Crossed-Beam and Theoretical Study

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