About: Redox potentials and binding enhancement of fullerene and fullerene-cyclodextrin systems in water and dimethylsulfoxide

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The formal redox potentials of electron transfer reactions of fullerene, methanofullerene, fullerene-cyclodextrin complex and methanofullerene conjugates with cyclodextrins in aqueous and dimethylsulfoxide solutions are reported. These new compounds are surface active and retain the redox activity of C-60 even in aqueous medium. Compounds have been characterized by an electrochemical admittance technique, which offers an advantage of separating faradaic and capacitive properties. Observed difference of formal redox potentials of the free fullerene forms and their cyclodextrin-containing compounds were used to determine the binding enhancement. Results are interpreted in terms of inter-molecular host-guest interactions of C-60-cyclodextrin conjugates. The formal redox potentials of electron transfer reactions of fullerene, methanofullerene, fullerene-cyclodextrin complex and methanofullerene conjugates with cyclodextrins in aqueous and dimethylsulfoxide solutions are reported. These new compounds are surface active and retain the redox activity of C-60 even in aqueous medium. Compounds have been characterized by an electrochemical admittance technique, which offers an advantage of separating faradaic and capacitive properties. Observed difference of formal redox potentials of the free fullerene forms and their cyclodextrin-containing compounds were used to determine the binding enhancement. Results are interpreted in terms of inter-molecular host-guest interactions of C-60-cyclodextrin conjugates. (en)
Title	Redox potentials and binding enhancement of fullerene and fullerene-cyclodextrin systems in water and dimethylsulfoxide Redox potentials and binding enhancement of fullerene and fullerene-cyclodextrin systems in water and dimethylsulfoxide (en)
skos:prefLabel	Redox potentials and binding enhancement of fullerene and fullerene-cyclodextrin systems in water and dimethylsulfoxide Redox potentials and binding enhancement of fullerene and fullerene-cyclodextrin systems in water and dimethylsulfoxide (en)
skos:notation	RIV/61388955:_____/10:00334005!RIV10-MSM-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/08/1157), P(GA203/09/0705), P(GP203/09/P502), P(LC510), P(ME09114), P(OC 140), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Pospíšil, Lubomír Sokolová, Romana Hromadová, Magdaléna Gál, Miroslav Bulíčková, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	284285
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/10:00334005
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	electrochemistry; fullerenes; fullerene-cyclodextrin systems (en)
http://linked.open.../riv/klicoveSlovo	electrochemistry fullerene-cyclodextrin systems fullerenes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[72EB0B6C78C3]
http://linked.open...i/riv/nazevZdroje	Carbon
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	10 (xsd:int)
http://linked.open...vavai/riv/projekt	Center of nanotechnology and materials for nanoelectronics Transfer of charge in single and assembled molecules Electrochemical Study of Redox Reactions of Radiosensitizers: Drugs that Make Radiation Work Better in Destroying Cancer Cells http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20140 Collaboration in Energy and Nanoscience Tailoring the lock and key motifs in novel low-dimensional structures at electrified interface
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	48
http://linked.open...iv/tvurceVysledku	Gál, Miroslav Hromadová, Magdaléna Pospíšil, Lubomír Sokolová, Romana Zhang, Y. Bulíčková, Jana Filippone, S. Guan, Z. Rassat, A. Yang, J.
http://linked.open...ain/vavai/riv/wos	000272018800019
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0008-6223
number of pages	10 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Redox potentials and binding enhancement of fullerene and fullerene-cyclodextrin systems in water and dimethylsulfoxide Redox potentials and binding enhancement of fullerene and fullerene-cyclodextrin systems in water and dimethylsulfoxide Redox potentials and binding enhancement of fullerene and fullerene-cyclodextrin systems in water and dimethylsulfoxide

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