About: Iso-nitrous acid radical cation in the gas phase: first experimental evidence

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Iso-nitrous acid radical cation in the gas phase: first experimental evidence Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The iso-nitrous acid radical-cation, HNO2+., was prepared for the first time by exothermic protonation of NO2 with H3+ and characterized by collisionally activated dissociation mass spectra. RRKM calculations that were based on B3LYP/6-311++G(3df,2pd) calculated energies and frequencies were consistent with experimental data that showed the loss of H• and HO• radicals to be the only two competitive fragmentation channels of HNO2+•. The iso-nitrous acid radical-cation, HNO2+., was prepared for the first time by exothermic protonation of NO2 with H3+ and characterized by collisionally activated dissociation mass spectra. RRKM calculations that were based on B3LYP/6-311++G(3df,2pd) calculated energies and frequencies were consistent with experimental data that showed the loss of H• and HO• radicals to be the only two competitive fragmentation channels of HNO2+•. (en) Exotermickou protonací NO2 pomocí H3+ byl poprvé připraven kation radikál izodusité kyseliny HNO2.sup+•, který byl charakterizován pomocí hmotnostních spekter získaných kolizně aktivovanou disociací. Výpočty RRKM s použitím energií a frekvencí vypočítaných metodou B3LYP/6311++G(3df,2pd) byly konzistentní s experimentálními daty, která ukázala, že ztráty H• a HO• jsou jediné dva kompetitivní fragmentační kanály iontu HNO2+•. (cs)
Title	Iso-nitrous acid radical cation in the gas phase: first experimental evidence Iso-nitrous acid radical cation in the gas phase: first experimental evidence (en) Kation radikál izodusité kyseliny v plynné fázi: první experimentální důkaz (cs)
skos:prefLabel	Iso-nitrous acid radical cation in the gas phase: first experimental evidence Iso-nitrous acid radical cation in the gas phase: first experimental evidence (en) Kation radikál izodusité kyseliny v plynné fázi: první experimentální důkaz (cs)
skos:notation	RIV/61388955:_____/05:00000577!RIV06-AV0-61388955
http://linked.open.../vavai/riv/strany	138;142
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/02/0737), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1-3
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Hrušák, Jan Polášek, Miroslav Kaczorowska, Malgorzata
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	525751
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/05:00000577
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	potential-energy surface; ab-initio; selective oxidation (en)
http://linked.open.../riv/klicoveSlovo	selective oxidation potential-energy surface ab-initio
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[1C692EAF92E6]
http://linked.open...i/riv/nazevZdroje	Chemical Physics Letters
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Mass spectrometric and theoretical characterization of transient molecules
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	402
http://linked.open...iv/tvurceVysledku	Polášek, Miroslav Hrušák, Jan Kaczorowska, Malgorzata
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0009-2614
number of pages	5 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Iso-nitrous acid radical cation in the gas phase: first experimental evidence

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software