| Attributes | Values |
|---|
| rdf:type
| |
| Description
| - Spojení fac-[Re(CO)(3)Cl] s komponenty ligandového redox systému bmtz/bmtz(-)-/H(2)bmtz/H(2)bmtz(-) (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazin) vedl k izolaci komplexů (H(2)bmtz)Re(CO)(3)Cl, (mu-H(2)bmtz)[Re(CO)(3)Cl](2) a (mu-bmtz)[Re(CO)(3)Cl](2). Dalšími charakterizovanými částicemi byly (bmtz)Re(CO)(3)Cl (UV/VIS, IR), [(H(2)bmtz)Re(CO)(3)Cl](.- ) (UV/VIS, IR, EPR), {(mu-H(2)bmtz)[Re(CO)(3)Cl](2)}(.- ) (UV/VIS, IR, EPR ) a {(mu-bmtz)[Re(CO)(3)Cl](2)}(.- ) (UV/VIS, IR, X band a high-field EPR). Výsledky potvrzují bmtz jako velmi silný a H(2)bmtz jako mírný pi-akceptorový ligand vyhledem k jednomu nebo dvama chelátově vázaným nízkovalentním kovovým centrům. Reaktivita odpovídá oxidativní disociaci protonu a reduktivní disociaci chloridu. (cs)
- Combining fac-[Re(CO)(3)Cl] with components of the ligand redox system bmtz/bmtz(-)-/H(2)bmtz/H(2)bmtz(-) (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine) has led to the isolation of the complexes (H(2)bmtz)Re(CO)(3)Cl, (mu-H(2)bmtz)[Re(CO)(3)Cl](2) and (mu-bmtz)[Re(CO)(3)Cl](2). Other species characterized were (bmtz)Re(CO)(3)Cl (UV/Vis, IR), [(H(2)bmtz)Re(CO)(3)Cl](.-) (UV/Vis, IR, EPR), {(mu-H(2)bmtz)[Re(CO)(3)Cl](2)}(.-) (UV/Vis, IR, EPR) and {(mu-bmtz)[Re(CO)(3)Cl](2)}(.-) (UV/Vis, IR, X band and high-field EPR). The results confirm bmtz as very strong and H(2)bmtz as moderate n acceptor ligand versus one or two chelate-bonded low-valent metal centers. Reactivity is observed in terms of oxidative proton and reductive chloride dissociation.
- Combining fac-[Re(CO)(3)Cl] with components of the ligand redox system bmtz/bmtz(-)-/H(2)bmtz/H(2)bmtz(-) (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine) has led to the isolation of the complexes (H(2)bmtz)Re(CO)(3)Cl, (mu-H(2)bmtz)[Re(CO)(3)Cl](2) and (mu-bmtz)[Re(CO)(3)Cl](2). Other species characterized were (bmtz)Re(CO)(3)Cl (UV/Vis, IR), [(H(2)bmtz)Re(CO)(3)Cl](.-) (UV/Vis, IR, EPR), {(mu-H(2)bmtz)[Re(CO)(3)Cl](2)}(.-) (UV/Vis, IR, EPR) and {(mu-bmtz)[Re(CO)(3)Cl](2)}(.-) (UV/Vis, IR, X band and high-field EPR). The results confirm bmtz as very strong and H(2)bmtz as moderate n acceptor ligand versus one or two chelate-bonded low-valent metal centers. Reactivity is observed in terms of oxidative proton and reductive chloride dissociation. (en)
|
| Title
| - Complexes of [Re(CO)3Cl] with Different Oxidation States of the Polyfunctional bmtz/H2bmtz Ligand System (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine)
- Complexes of [Re(CO)3Cl] with Different Oxidation States of the Polyfunctional bmtz/H2bmtz Ligand System (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine) (en)
- Komplexy [Re(CO)3Cl ] s různými oxidačními stavy polyfunkčního ligandového systému bmtz/H2bmtz (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazin) (cs)
|
| skos:prefLabel
| - Complexes of [Re(CO)3Cl] with Different Oxidation States of the Polyfunctional bmtz/H2bmtz Ligand System (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine)
- Complexes of [Re(CO)3Cl] with Different Oxidation States of the Polyfunctional bmtz/H2bmtz Ligand System (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine) (en)
- Komplexy [Re(CO)3Cl ] s různými oxidačními stavy polyfunkčního ligandového systému bmtz/H2bmtz (bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazin) (cs)
|
| skos:notation
| - RIV/61388955:_____/04:00107598!RIV/2005/AV0/A54005/N
|
| http://linked.open.../vavai/riv/strany
| |
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(OC D14.20), P(OC D15.10), Z(AV0Z4040901)
|
| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
| |
| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/04:00107598
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - cyclic voltammetry; EPR; Rhenium complexes (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
|
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| |
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Fiedler, Jan
- Kaim, W.
- Frantz, S.
- Duboc, K.
|
| http://linked.open...n/vavai/riv/zamer
| |
| issn
| |
| number of pages
| |
![[RDF Data]](/fct/images/sw-rdf-blue.png)
![[cxml]](/fct/images/cxml_doc.png)
![[csv]](/fct/images/csv_doc.png)
![[text]](/fct/images/ntriples_doc.png)
![[turtle]](/fct/images/n3turtle_doc.png)
![[ld+json]](/fct/images/jsonld_doc.png)
![[rdf+json]](/fct/images/json_doc.png)
![[rdf+xml]](/fct/images/xml_doc.png)
![[atom+xml]](/fct/images/atom_doc.png)
![[html]](/fct/images/html_doc.png)