| Attributes | Values |
|---|
| rdf:type
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| Description
| - 12C14N vibračně-rotační pás pro sekvence 1-0 až 9-8 byly pozorovány ve spektrální oblasti 1800-2200 cm-1 pomocí Bruker 120 HR Fourier transform spektrometru s neapodizovaným rozlišením 0.027 cm-1. Bylo pozorováno 362 linií a z toho 237 linií bylo fitováno pomocí nejmenších čtverců pomocí Dunhamových expanzních koeficientů s čtvercem odchylek 0.00093 cm-1. dohromady se všemi nejpřesnějšími daty z literatury byly naše linie fitovány v rámci metody redukovaných potenciálních křivek (RPC).Získaná globální potenciální energetická funkce poskytuje velice kvantitativní popis experimentálních až do 30 000 cm-1. Globální fit RPC byl navíc použit pro plně kvantitativní fit dat třech nejnižších vibračních stavů. Obdržené efektivní potenciální křiv dovolují velice přesné predikce vysoce excitovaných rotačních stavů. (cs)
- C-12(14) N vibration-rotation bands for the sequences (1-0) through (9-8) were observed in the spectral region 1800-2200 cm(-1) using a Bruker 120 HR Fourier transform spectrometer at an unapodized resolution of 0.027 cm(-1). Of the 362 lines observed, the wavenumbers of 237 lines were least-squares fitted using the Dunham expansion coefficients with a root-mean-square deviation of 0.00093 cm(-1). Together with most accurate data from the literature, the data were also fitted in the framework of the reduced potential curve (RPC) method. The global potential energy function resulting from this fit provides a fairly quantitative description of the experimental data, at least up to 30000 cm(-1). In addition to global fitting, the RPC approach was also used for fully quantitative fitting of the data pertaining to the lowest three vibrational states. The effective potential energy curves obtained in this way allow for very accurate predictions of highly excited rotational states.
- C-12(14) N vibration-rotation bands for the sequences (1-0) through (9-8) were observed in the spectral region 1800-2200 cm(-1) using a Bruker 120 HR Fourier transform spectrometer at an unapodized resolution of 0.027 cm(-1). Of the 362 lines observed, the wavenumbers of 237 lines were least-squares fitted using the Dunham expansion coefficients with a root-mean-square deviation of 0.00093 cm(-1). Together with most accurate data from the literature, the data were also fitted in the framework of the reduced potential curve (RPC) method. The global potential energy function resulting from this fit provides a fairly quantitative description of the experimental data, at least up to 30000 cm(-1). In addition to global fitting, the RPC approach was also used for fully quantitative fitting of the data pertaining to the lowest three vibrational states. The effective potential energy curves obtained in this way allow for very accurate predictions of highly excited rotational states. (en)
|
| Title
| - The Infrared Spectrum of CN in Its Ground Electronic State
- Infračervené spektrum CN v jeho základním elektronickém stavu (cs)
- The Infrared Spectrum of CN in Its Ground Electronic State (en)
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| skos:prefLabel
| - The Infrared Spectrum of CN in Its Ground Electronic State
- Infračervené spektrum CN v jeho základním elektronickém stavu (cs)
- The Infrared Spectrum of CN in Its Ground Electronic State (en)
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| skos:notation
| - RIV/61388955:_____/04:00101127!RIV/2005/AV0/A54005/N
|
| http://linked.open.../vavai/riv/strany
| |
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(GA203/01/0618), P(LN00A032), Z(AV0Z4040901)
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| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
| |
| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/04:00101127
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - rotation-vibration; CN radical; IR spectroscopy (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Collection of Czechoslovak Chemical Communications
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Civiš, Svatopluk
- Kawaguchi, K.
- Špirko, Vladimír
- Horká, Veronika
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| http://linked.open...n/vavai/riv/zamer
| |
| issn
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| number of pages
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